Immobilization of Pb2+ with ordinary portland cement - The method using lead hydroxyapatite

Jae Woo Cho; Koji Ioku; Seishi Goto

doi:10.2109/jcersj.105.650

Immobilization of Pb²⁺ with ordinary portland cement - The method using lead hydroxyapatite

Jae Woo Cho, Koji Ioku, Seishi Goto

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Lead hydroxyapatite was synthesized hydrothermally at 150°C under saturated vapor pressure for 1h. This apatite or lead nitrate solution was added to ordinary portland cement (OPC) in order to immobilize the Pb²⁺. In this paper, the effect of Pb²⁺ on the hydration of OPC, mechanical properties of OPC pastes and the leaching characteristic of Pb²⁺ from hardened pastes were investigated. An addition of lead hydroxyapatite did not affect the hydration of OPC significantly, while that of lead nitrate solution affected the hydration of OPC. Therefore, a larger amount of Pb²⁺ could be immobilized by cement paste with lead hydroxyapatite than that with lead nitrate solution. The strength for hardened paste with lead hydroxyapatite was larger than that with nitrate solution. According to the leaching test for pastes, the apparent diffusion coefficient of Pb²⁺ in the paste with lead hydroxyapatite was smaller than that of Pb²⁺ in the paste with addition of lead nitrate solution.

Original language	English
Pages (from-to)	650-654
Number of pages	5
Journal	Journal of the Ceramic Society of Japan
Volume	105
Issue number	8
DOIs	https://doi.org/10.2109/jcersj.105.650
Publication status	Published - 1997 Aug
Externally published	Yes

Keywords

(Pb(PO)(OH))
Immobilization
Lead hydroxyapatite
Ordinary portland cement (OPC)
Pb

ASJC Scopus subject areas

Ceramics and Composites
Chemistry(all)
Condensed Matter Physics
Materials Chemistry

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title = "Immobilization of Pb2+ with ordinary portland cement - The method using lead hydroxyapatite",

abstract = "Lead hydroxyapatite was synthesized hydrothermally at 150°C under saturated vapor pressure for 1h. This apatite or lead nitrate solution was added to ordinary portland cement (OPC) in order to immobilize the Pb2+. In this paper, the effect of Pb2+ on the hydration of OPC, mechanical properties of OPC pastes and the leaching characteristic of Pb2+ from hardened pastes were investigated. An addition of lead hydroxyapatite did not affect the hydration of OPC significantly, while that of lead nitrate solution affected the hydration of OPC. Therefore, a larger amount of Pb2+ could be immobilized by cement paste with lead hydroxyapatite than that with lead nitrate solution. The strength for hardened paste with lead hydroxyapatite was larger than that with nitrate solution. According to the leaching test for pastes, the apparent diffusion coefficient of Pb2+ in the paste with lead hydroxyapatite was smaller than that of Pb2+ in the paste with addition of lead nitrate solution.",

keywords = "(Pb(PO)(OH)), Immobilization, Lead hydroxyapatite, Ordinary portland cement (OPC), Pb",

author = "Cho, {Jae Woo} and Koji Ioku and Seishi Goto",

year = "1997",

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doi = "10.2109/jcersj.105.650",

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AU - Cho, Jae Woo

AU - Ioku, Koji

AU - Goto, Seishi

PY - 1997/8

Y1 - 1997/8

N2 - Lead hydroxyapatite was synthesized hydrothermally at 150°C under saturated vapor pressure for 1h. This apatite or lead nitrate solution was added to ordinary portland cement (OPC) in order to immobilize the Pb2+. In this paper, the effect of Pb2+ on the hydration of OPC, mechanical properties of OPC pastes and the leaching characteristic of Pb2+ from hardened pastes were investigated. An addition of lead hydroxyapatite did not affect the hydration of OPC significantly, while that of lead nitrate solution affected the hydration of OPC. Therefore, a larger amount of Pb2+ could be immobilized by cement paste with lead hydroxyapatite than that with lead nitrate solution. The strength for hardened paste with lead hydroxyapatite was larger than that with nitrate solution. According to the leaching test for pastes, the apparent diffusion coefficient of Pb2+ in the paste with lead hydroxyapatite was smaller than that of Pb2+ in the paste with addition of lead nitrate solution.

AB - Lead hydroxyapatite was synthesized hydrothermally at 150°C under saturated vapor pressure for 1h. This apatite or lead nitrate solution was added to ordinary portland cement (OPC) in order to immobilize the Pb2+. In this paper, the effect of Pb2+ on the hydration of OPC, mechanical properties of OPC pastes and the leaching characteristic of Pb2+ from hardened pastes were investigated. An addition of lead hydroxyapatite did not affect the hydration of OPC significantly, while that of lead nitrate solution affected the hydration of OPC. Therefore, a larger amount of Pb2+ could be immobilized by cement paste with lead hydroxyapatite than that with lead nitrate solution. The strength for hardened paste with lead hydroxyapatite was larger than that with nitrate solution. According to the leaching test for pastes, the apparent diffusion coefficient of Pb2+ in the paste with lead hydroxyapatite was smaller than that of Pb2+ in the paste with addition of lead nitrate solution.

KW - (Pb(PO)(OH))

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KW - Lead hydroxyapatite

KW - Ordinary portland cement (OPC)

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