Improvement in Cobalt Phosphate Electrocatalyst Activity toward Oxygen Evolution from Water by Glycine Molecule Addition and Functional Details

Kanta Yamada, Tomoki Hiue, Toshiaki Ina, Kehsuan Wang, Hiroshi Kondoh, Yoshihisa Sakata, Yuh Lang Lee, Takeshi Kawai, Masaaki Yoshida

Research output: Contribution to journalArticle

Abstract

Electrochemical water splitting using renewable energy shows promise for the development of sustainable hydrogen production methods. The process requires a highly active electrocatalyst for oxygen evolution to improve the overall water splitting efficiency. The present study showed that oxygen evolution improved dramatically upon the addition of glycine to cobalt phosphate, when the glycine was added to the electrolyte solution during electrodeposition. The functionality of the organic molecules was investigated using in situ UV-vis absorption, in situ X-ray absorption fine structure, and in situ infrared (IR) absorption spectroscopy in the attenuated total reflection mode. The results demonstrated that the glycine molecules assembled cobalt oxide clusters composed of CoO6 (CoOOH) octahedrons a few nanometers in diameter upon the electrodeposition of cobalt catalysts. This suggests that the cobalt-glycine catalyst can decompose water to oxygen gas efficiently, because the number of cobalt oxide clusters increased as active reaction sites upon the addition of glycine molecules.

Original languageEnglish
Pages (from-to)35-40
Number of pages6
JournalAnalytical sciences : the international journal of the Japan Society for Analytical Chemistry
Volume36
Issue number1
DOIs
Publication statusPublished - 2020 Jan 10

Fingerprint

Electrocatalysts
Cobalt
Glycine
Phosphates
Oxygen
Molecules
Water
Electrodeposition
Catalysts
X ray absorption
Infrared absorption
Hydrogen production
Absorption spectroscopy
Electrolytes
Infrared spectroscopy
Reactive Oxygen Species
Gases
cobalt oxide

Keywords

  • cobalt phosphate
  • electrocatalysts
  • glycine
  • in-situ
  • IR
  • oxygen evolution
  • UV-vis
  • Water splitting
  • XAFS

ASJC Scopus subject areas

  • Analytical Chemistry

Cite this

Improvement in Cobalt Phosphate Electrocatalyst Activity toward Oxygen Evolution from Water by Glycine Molecule Addition and Functional Details. / Yamada, Kanta; Hiue, Tomoki; Ina, Toshiaki; Wang, Kehsuan; Kondoh, Hiroshi; Sakata, Yoshihisa; Lee, Yuh Lang; Kawai, Takeshi; Yoshida, Masaaki.

In: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, Vol. 36, No. 1, 10.01.2020, p. 35-40.

Research output: Contribution to journalArticle

Yamada, Kanta ; Hiue, Tomoki ; Ina, Toshiaki ; Wang, Kehsuan ; Kondoh, Hiroshi ; Sakata, Yoshihisa ; Lee, Yuh Lang ; Kawai, Takeshi ; Yoshida, Masaaki. / Improvement in Cobalt Phosphate Electrocatalyst Activity toward Oxygen Evolution from Water by Glycine Molecule Addition and Functional Details. In: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry. 2020 ; Vol. 36, No. 1. pp. 35-40.
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AU - Wang, Kehsuan

AU - Kondoh, Hiroshi

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