Indirect cation-flow method: Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations

Kodai Saito, Koji Ueoka, Kouichi Matsumoto, Seiji Suga, Toshiki Nokami, Jun Ichi Yoshida

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

Go with the flow: The indirect cation-flow method based on the generation of highly reactive organic cations from their precursors using electrochemically generated [ArS(ArSSAr)]+ was developed in flow microreactor systems (see scheme; Bn=benzyl, M=micromixer, R=microtube reactor). The method was applied to evaluate glycosyl cations such as A or their equivalents and glycosylation reactions.

Original languageEnglish
Pages (from-to)5153-5156
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number22
DOIs
Publication statusPublished - 2011 May 23
Externally publishedYes

Keywords

  • carbohydrates
  • cations
  • electrochemistry
  • microreactors
  • sulfur

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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