Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer

Masaaki Mitsui, Shingo Doi, Kaori Ikemoto, Shuhei Nagaoka, Atsushi Nakajima

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Gas-phase synthesized vanadium-mesitylene 1:2 V(mes)2 cluster cations were size-selectively deposited onto a long-chain alkanethiolate selfassembled monolayer-coated gold substrate under ultrahigh vacuum conditions. Examination of the resultant clusters was conducted by infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD), showing the clusters molecularly adsorbed and maintaining a sandwich structure on the substrate.

Original languageEnglish
Title of host publicationLatest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale
PublisherImperial College Press
Pages199-204
Number of pages6
ISBN (Print)9781848162389, 9781848162372
DOIs
Publication statusPublished - 2008 Jan 1

Fingerprint

Vanadium
Thermal desorption
Self assembled monolayers
Vacuum
Gold
Cations
Infrared spectroscopy
Spectrum Analysis
Hot Temperature
Gases
desorption
infrared spectroscopy
Temperature
Sandwich structures
Ultrahigh vacuum
Substrates
Temperature programmed desorption
Absorption spectroscopy
mesitylene
Monolayers

Keywords

  • Cluster
  • Self-assembled monolayer
  • Soft-landing

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)
  • Chemistry(all)
  • Physics and Astronomy(all)

Cite this

Mitsui, M., Doi, S., Ikemoto, K., Nagaoka, S., & Nakajima, A. (2008). Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. In Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale (pp. 199-204). Imperial College Press. https://doi.org/10.1142/9781848162389_0016

Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1 : 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. / Mitsui, Masaaki; Doi, Shingo; Ikemoto, Kaori; Nagaoka, Shuhei; Nakajima, Atsushi.

Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press, 2008. p. 199-204.

Research output: Chapter in Book/Report/Conference proceedingChapter

Mitsui, M, Doi, S, Ikemoto, K, Nagaoka, S & Nakajima, A 2008, Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. in Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press, pp. 199-204. https://doi.org/10.1142/9781848162389_0016
Mitsui M, Doi S, Ikemoto K, Nagaoka S, Nakajima A. Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. In Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press. 2008. p. 199-204 https://doi.org/10.1142/9781848162389_0016
Mitsui, Masaaki ; Doi, Shingo ; Ikemoto, Kaori ; Nagaoka, Shuhei ; Nakajima, Atsushi. / Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1 : 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press, 2008. pp. 199-204
@inbook{10979624b2bf4a3ba7ad1d4f083e0a33,
title = "Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer",
abstract = "Gas-phase synthesized vanadium-mesitylene 1:2 V(mes)2 cluster cations were size-selectively deposited onto a long-chain alkanethiolate selfassembled monolayer-coated gold substrate under ultrahigh vacuum conditions. Examination of the resultant clusters was conducted by infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD), showing the clusters molecularly adsorbed and maintaining a sandwich structure on the substrate.",
keywords = "Cluster, Self-assembled monolayer, Soft-landing",
author = "Masaaki Mitsui and Shingo Doi and Kaori Ikemoto and Shuhei Nagaoka and Atsushi Nakajima",
year = "2008",
month = "1",
day = "1",
doi = "10.1142/9781848162389_0016",
language = "English",
isbn = "9781848162389",
pages = "199--204",
booktitle = "Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale",
publisher = "Imperial College Press",

}

TY - CHAP

T1 - Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1

T2 - 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer

AU - Mitsui, Masaaki

AU - Doi, Shingo

AU - Ikemoto, Kaori

AU - Nagaoka, Shuhei

AU - Nakajima, Atsushi

PY - 2008/1/1

Y1 - 2008/1/1

N2 - Gas-phase synthesized vanadium-mesitylene 1:2 V(mes)2 cluster cations were size-selectively deposited onto a long-chain alkanethiolate selfassembled monolayer-coated gold substrate under ultrahigh vacuum conditions. Examination of the resultant clusters was conducted by infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD), showing the clusters molecularly adsorbed and maintaining a sandwich structure on the substrate.

AB - Gas-phase synthesized vanadium-mesitylene 1:2 V(mes)2 cluster cations were size-selectively deposited onto a long-chain alkanethiolate selfassembled monolayer-coated gold substrate under ultrahigh vacuum conditions. Examination of the resultant clusters was conducted by infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD), showing the clusters molecularly adsorbed and maintaining a sandwich structure on the substrate.

KW - Cluster

KW - Self-assembled monolayer

KW - Soft-landing

UR - http://www.scopus.com/inward/record.url?scp=84967355772&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84967355772&partnerID=8YFLogxK

U2 - 10.1142/9781848162389_0016

DO - 10.1142/9781848162389_0016

M3 - Chapter

AN - SCOPUS:84967355772

SN - 9781848162389

SN - 9781848162372

SP - 199

EP - 204

BT - Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale

PB - Imperial College Press

ER -