Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes

Masaki Okamoto, Satoshi Onodera, Tomoki Okano, Eiichi Suzuki, Yoshio Ono

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.

Original languageEnglish
Pages (from-to)67-71
Number of pages5
JournalJournal of Organometallic Chemistry
Volume531
Issue number1-2
DOIs
Publication statusPublished - 1997 Mar 15
Externally publishedYes

Fingerprint

Methyl Chloride
methyl chloride
Silicon
silicon
synthesis
products
butadiene
Butadiene
selectivity

Keywords

  • Alkyl halide
  • Catalysis
  • Copper
  • Silane
  • Silicon
  • Silylene

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes. / Okamoto, Masaki; Onodera, Satoshi; Okano, Tomoki; Suzuki, Eiichi; Ono, Yoshio.

In: Journal of Organometallic Chemistry, Vol. 531, No. 1-2, 15.03.1997, p. 67-71.

Research output: Contribution to journalArticle

Okamoto, Masaki ; Onodera, Satoshi ; Okano, Tomoki ; Suzuki, Eiichi ; Ono, Yoshio. / Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes. In: Journal of Organometallic Chemistry. 1997 ; Vol. 531, No. 1-2. pp. 67-71.
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