Interplay of diamides and rare earth metals: Specific molecular spaces and catalytic activity

Naoya Kumagai; Masakatsu Shibasaki

doi:10.1007/978-981-13-1256-4_7

Interplay of diamides and rare earth metals: Specific molecular spaces and catalytic activity

Naoya Kumagai, Masakatsu Shibasaki

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

A catalytic system comprising functionalized small diamides and rare earth metals (REs) exerts intriguing catalytic properties that are dictated by dynamic construction of flexible molecular spaces. The dynamic interaction of diamides and REs is characterized by broad applicability to distinct reaction systems as well as notable switchable catalysis. Structural modification of the diamide allows for enhanced intermolecular interactions to afford a self-assembled solid-phase catalyst with a specific molecular space that engages in heterogeneous asymmetric catalysis with a continuous-flow platform.

Original language	English
Title of host publication	Designed Molecular Space in Material Science and Catalysis
Publisher	Springer Singapore
Pages	147-163
Number of pages	17
ISBN (Electronic)	9789811312564
ISBN (Print)	9789811312557
DOIs	https://doi.org/10.1007/978-981-13-1256-4_7
Publication status	Published - 2018 Jan 1
Externally published	Yes

Keywords

Asymmetric catalysis
Diamide
Photoisomerization
Rare earth metals (REs)
Selfassembly

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)
Engineering(all)
Chemistry(all)
Chemical Engineering(all)

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10.1007/978-981-13-1256-4_7

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AB - A catalytic system comprising functionalized small diamides and rare earth metals (REs) exerts intriguing catalytic properties that are dictated by dynamic construction of flexible molecular spaces. The dynamic interaction of diamides and REs is characterized by broad applicability to distinct reaction systems as well as notable switchable catalysis. Structural modification of the diamide allows for enhanced intermolecular interactions to afford a self-assembled solid-phase catalyst with a specific molecular space that engages in heterogeneous asymmetric catalysis with a continuous-flow platform.

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KW - Photoisomerization

KW - Rare earth metals (REs)

KW - Selfassembly

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ER -

Interplay of diamides and rare earth metals: Specific molecular spaces and catalytic activity

Abstract

Keywords

ASJC Scopus subject areas

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