Intramolecular chirality transfer in irans-5,6-Diaryl-5,6-dihydro-l,10- phenanthroline-5,6-diols: Solvato- And halochromic responses by circular dichroism

Takanori Suzuki, Youhei Miura, Tatsuo Nehira, Hidetoshi Kawai, Kenshu Fujiwara

Research output: Contribution to journalArticle

Abstract

Not only the configuration at the C5 and C6 stereocenters but also the intra/intermoleculer hydrogen-bonding mode are determinant for the sense of mobile helicity of the dihydrophenanthroline unit in the title diols in solution. Thus, drastic changes in chiroptical signals are induced through conformational switching of 1 upon addition of protic solvent and/or acid.

Original languageEnglish
Pages (from-to)695-697
Number of pages3
JournalChemistry Letters
Volume39
Issue number7
DOIs
Publication statusPublished - 2010 Jul 12

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ASJC Scopus subject areas

  • Chemistry(all)

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