Intramolecular cyclization of m-homoprenylphenols through oxidative nucleophilic aromatic substitution

Hiroki Deguchi, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi

Research output: Contribution to journalArticlepeer-review

Abstract

We developed an intramolecular cyclization of m-homoprenylphenols and related m-prenylphenols to bicyclic skeletons by hypervalent iodine reagents through an oxidative nucleophilic aromatic substitution using the prenyl group as a carbon nucleophile. The reaction was applicable for the syntheses of 5/6-, 6/6-, and 7/6-fused ring systems.

Original languageEnglish
Pages (from-to)748-751
Number of pages4
JournalChemical Communications
Volume59
Issue number6
DOIs
Publication statusPublished - 2022 Dec 15

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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