Intramolecular direct aldol reactions of sugar 2,7-diketones: Syntheses of hydroxylated cycloalka(e)nones

Tony K.M. Shing; Hau M. Cheng

doi:10.1039/c5ob00253b

Intramolecular direct aldol reactions of sugar 2,7-diketones: Syntheses of hydroxylated cycloalka(e)nones

Tony K.M. Shing, Hau M. Cheng

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A regio- and stereoselective intramolecular direct aldol reaction of 2,7-diketones derived from carbohydrates has been developed to construct cycloalkanones 7, which were dehydrated to obtain heavily oxygenated cycloalkenones 8.

Original language	English
Pages (from-to)	4795-4802
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	16
DOIs	https://doi.org/10.1039/c5ob00253b
Publication status	Published - 2015 Apr 28

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1039/c5ob00253b

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title = "Intramolecular direct aldol reactions of sugar 2,7-diketones: Syntheses of hydroxylated cycloalka(e)nones",

abstract = "A regio- and stereoselective intramolecular direct aldol reaction of 2,7-diketones derived from carbohydrates has been developed to construct cycloalkanones 7, which were dehydrated to obtain heavily oxygenated cycloalkenones 8.",

author = "Shing, {Tony K.M.} and Cheng, {Hau M.}",

year = "2015",

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doi = "10.1039/c5ob00253b",

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T2 - Syntheses of hydroxylated cycloalka(e)nones

AU - Shing, Tony K.M.

AU - Cheng, Hau M.

PY - 2015/4/28

Y1 - 2015/4/28

N2 - A regio- and stereoselective intramolecular direct aldol reaction of 2,7-diketones derived from carbohydrates has been developed to construct cycloalkanones 7, which were dehydrated to obtain heavily oxygenated cycloalkenones 8.

AB - A regio- and stereoselective intramolecular direct aldol reaction of 2,7-diketones derived from carbohydrates has been developed to construct cycloalkanones 7, which were dehydrated to obtain heavily oxygenated cycloalkenones 8.

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DO - 10.1039/c5ob00253b

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JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

SN - 1477-0520

IS - 16

ER -

Intramolecular direct aldol reactions of sugar 2,7-diketones: Syntheses of hydroxylated cycloalka(e)nones

Abstract

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