Intramolecular direct aldol reactions of sugar 2,7-diketones: Syntheses of hydroxylated cycloalka(e)nones

Tony K.M. Shing; Hau M. Cheng

doi:10.1039/c5ob00253b

Intramolecular direct aldol reactions of sugar 2,7-diketones: Syntheses of hydroxylated cycloalka(e)nones

Tony K.M. Shing, Hau M. Cheng

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A regio- and stereoselective intramolecular direct aldol reaction of 2,7-diketones derived from carbohydrates has been developed to construct cycloalkanones 7, which were dehydrated to obtain heavily oxygenated cycloalkenones 8.

Original language	English
Pages (from-to)	4795-4802
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	16
DOIs	https://doi.org/10.1039/c5ob00253b
Publication status	Published - 2015 Apr 28

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Intramolecular direct aldol reactions of sugar 2,7-diketones: Syntheses of hydroxylated cycloalka(e)nones",

abstract = "A regio- and stereoselective intramolecular direct aldol reaction of 2,7-diketones derived from carbohydrates has been developed to construct cycloalkanones 7, which were dehydrated to obtain heavily oxygenated cycloalkenones 8.",

author = "Shing, {Tony K.M.} and Cheng, {Hau M.}",

year = "2015",

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AU - Cheng, Hau M.

PY - 2015/4/28

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AB - A regio- and stereoselective intramolecular direct aldol reaction of 2,7-diketones derived from carbohydrates has been developed to construct cycloalkanones 7, which were dehydrated to obtain heavily oxygenated cycloalkenones 8.

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