Intramolecular reaction of electrogenerated phenoxy cations with an olefin bearing an electron-releasing group at the side chain

Shojiro Maki, Toshiyuki Suzuki, Seiji Kosemura, Yoshikazu Shizuri, Shosuke Yamamura

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Some phenols with an olefinic side chain have been electrolyzed under various conditions to afford both intramolecular [5 + 1]cycloaddition products and spiro compounds depending on solvent, substituents on the olefinic double bond and others. These rection products are regarded as a synthetic key intermediate of bioactive terpenoids.

Original languageEnglish
Pages (from-to)4973-4976
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number37
DOIs
Publication statusPublished - 1991 Sep 9

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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