Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid

Yoshiki Ohgo, Saburo Neya, Masashi Takahashi, Masuo Takeda, Noriaki Funasaki, Mikio Nakamura

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Although iodo(etiohemiporphycenato)iron(III) showed an admixed intermediate-spin state (S = 3/2, 5/2) with a major contribution of S = 3/2 in solution, the same complex exhibited the high-spin state (S = 5/2) in the solid phase. Importance of the crystal packing has been pointed out for the formation of the high-spin complex in the solid.

Original languageEnglish
Pages (from-to)526-527
Number of pages2
JournalChemistry Letters
Volume32
Issue number6
Publication statusPublished - 2003 Jun 5

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Ohgo, Y., Neya, S., Takahashi, M., Takeda, M., Funasaki, N., & Nakamura, M. (2003). Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid. Chemistry Letters, 32(6), 526-527.

Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid. / Ohgo, Yoshiki; Neya, Saburo; Takahashi, Masashi; Takeda, Masuo; Funasaki, Noriaki; Nakamura, Mikio.

In: Chemistry Letters, Vol. 32, No. 6, 05.06.2003, p. 526-527.

Research output: Contribution to journalArticle

Ohgo, Y, Neya, S, Takahashi, M, Takeda, M, Funasaki, N & Nakamura, M 2003, 'Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid', Chemistry Letters, vol. 32, no. 6, pp. 526-527.
Ohgo Y, Neya S, Takahashi M, Takeda M, Funasaki N, Nakamura M. Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid. Chemistry Letters. 2003 Jun 5;32(6):526-527.
Ohgo, Yoshiki ; Neya, Saburo ; Takahashi, Masashi ; Takeda, Masuo ; Funasaki, Noriaki ; Nakamura, Mikio. / Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid. In: Chemistry Letters. 2003 ; Vol. 32, No. 6. pp. 526-527.
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