Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid

Yoshiki Ohgo, Saburo Neya, Masashi Takahashi, Masuo Takeda, Noriaki Funasaki, Mikio Nakamura

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13 Citations (Scopus)

Abstract

Although iodo(etiohemiporphycenato)iron(III) showed an admixed intermediate-spin state (S = 3/2, 5/2) with a major contribution of S = 3/2 in solution, the same complex exhibited the high-spin state (S = 5/2) in the solid phase. Importance of the crystal packing has been pointed out for the formation of the high-spin complex in the solid.

Original languageEnglish
Pages (from-to)526-527
Number of pages2
JournalChemistry Letters
Volume32
Issue number6
DOIs
Publication statusPublished - 2003 Jun 5

ASJC Scopus subject areas

  • Chemistry(all)

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    Ohgo, Y., Neya, S., Takahashi, M., Takeda, M., Funasaki, N., & Nakamura, M. (2003). Iodo(etiohemiporphycenato)iron(III). Unexpected difference in magnetic behavior in solution and solid. Chemistry Letters, 32(6), 526-527. https://doi.org/10.1246/cl.2003.526