@article{56aaa45040a04f25b84fa1462cd7eb07,
title = "Iron-Catalyzed Ortho-Selective C−H Alkylation of Aromatic Ketones with N-Alkenylindoles and Partial Indolylation via 1,4-Iron Migration",
abstract = "An ortho-selective C−H alkylation of aromatic ketones with N-alkenylindoles proceeded in the presence of just a Fe(PMe3)4 catalyst. In addition, C−H indolylation products, which are considered to be formed via 1,4-iron migration, were also observed as minor products.",
keywords = "C−H activation, alkylation, heterocycles, iron, ketones",
author = "Naoki Kimura and Takuya Kochi and Fumitoshi Kakiuchi",
note = "Funding Information: This work was supported in part by JSPS KAKENHI Grant Numbers JP15H05839 (Middle Molecular Strategy) and JP17K19126, and by the Research Program of ?Five-star Alliance? in ?NJRC Mater. & Dev.? T.K. is also grateful to the support by JSPS KAKENHI Grant Number JP18H04271 (Precisely Designed Catalysts with Customized Scaffolding). N.K. is also grateful for support by Keio University Doctorate Student Grant-in-Aid Program, and by the Japan Society for the Promotion of Science (JSPS) for a Research Fellowship for Young Scientists (JP19J12813). Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2019",
month = jul,
doi = "10.1002/ajoc.201900209",
language = "English",
volume = "8",
pages = "1115--1117",
journal = "Asian Journal of Organic Chemistry",
issn = "2193-5807",
publisher = "Wiley - VCH Verlag GmbH & CO. KGaA",
number = "7",
}