Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base

Yuta Sadamitsu; Akira Okumura; Kodai Saito; Tohru Yamada

doi:10.1039/c9cc04550c

Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base

Yuta Sadamitsu, Akira Okumura, Kodai Saito, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The combined use of an organic base for resorcinols realized a Kolbe-Schmitt type reaction under ambient conditions. When resorcinols (3-hydroxyphenol derivatives) were treated with DBU under a carbon dioxide atmosphere, nucleophilic addition to carbon dioxide proceeded to afford the corresponding salicylic acid derivatives in high yields.

Original language	English
Pages (from-to)	9837-9840
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	66
DOIs	https://doi.org/10.1039/c9cc04550c
Publication status	Published - 2019 Jan 1

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base",

abstract = "The combined use of an organic base for resorcinols realized a Kolbe-Schmitt type reaction under ambient conditions. When resorcinols (3-hydroxyphenol derivatives) were treated with DBU under a carbon dioxide atmosphere, nucleophilic addition to carbon dioxide proceeded to afford the corresponding salicylic acid derivatives in high yields.",

author = "Yuta Sadamitsu and Akira Okumura and Kodai Saito and Tohru Yamada",

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AU - Okumura, Akira

AU - Saito, Kodai

AU - Yamada, Tohru

PY - 2019/1/1

Y1 - 2019/1/1

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AB - The combined use of an organic base for resorcinols realized a Kolbe-Schmitt type reaction under ambient conditions. When resorcinols (3-hydroxyphenol derivatives) were treated with DBU under a carbon dioxide atmosphere, nucleophilic addition to carbon dioxide proceeded to afford the corresponding salicylic acid derivatives in high yields.

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Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base

Abstract

ASJC Scopus subject areas

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