Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base

Yuta Sadamitsu, Akira Okumura, Kodai Saito, Tohru Yamada

Research output: Contribution to journalArticle

Abstract

The combined use of an organic base for resorcinols realized a Kolbe-Schmitt type reaction under ambient conditions. When resorcinols (3-hydroxyphenol derivatives) were treated with DBU under a carbon dioxide atmosphere, nucleophilic addition to carbon dioxide proceeded to afford the corresponding salicylic acid derivatives in high yields.

Original languageEnglish
Pages (from-to)9837-9840
Number of pages4
JournalChemical Communications
Volume55
Issue number66
DOIs
Publication statusPublished - 2019 Jan 1

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Resorcinols
Carbon Dioxide
Carbon dioxide
Derivatives
Salicylic acid
Salicylic Acid

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base. / Sadamitsu, Yuta; Okumura, Akira; Saito, Kodai; Yamada, Tohru.

In: Chemical Communications, Vol. 55, No. 66, 01.01.2019, p. 9837-9840.

Research output: Contribution to journalArticle

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