Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base

Yuta Sadamitsu; Akira Okumura; Kodai Saito; Tohru Yamada

doi:10.1039/c9cc04550c

Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base

Yuta Sadamitsu, Akira Okumura, Kodai Saito, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article

Abstract

The combined use of an organic base for resorcinols realized a Kolbe-Schmitt type reaction under ambient conditions. When resorcinols (3-hydroxyphenol derivatives) were treated with DBU under a carbon dioxide atmosphere, nucleophilic addition to carbon dioxide proceeded to afford the corresponding salicylic acid derivatives in high yields.

Original language	English
Pages (from-to)	9837-9840
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	66
DOIs	https://doi.org/10.1039/c9cc04550c
Publication status	Published - 2019 Jan 1

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Sadamitsu, Y., Okumura, A., Saito, K., & Yamada, T. (2019). Kolbe-Schmitt type reaction under ambient conditions mediated by an organic base. Chemical Communications, 55(66), 9837-9840. https://doi.org/10.1039/c9cc04550c

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Access to Document

10.1039/c9cc04550c