Lanthanide organometallic sandwich nanowires: Formation mechanism

Natsuki Hosoya, Ryuta Takegami, Jun Ichi Suzumura, Keizo Yada, Kiichirou Koyasu, Ken Miyajima, Masaaki Mitsui, Mark B. Knickelbein, Satoshi Yabushita, Atsushi Nakajima

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Abstract

A molecular beam of europium-cyclooctatetraene sandwich nanowires Eu n(COT) m was produced by a laser vaporization synthesis method. The formation mechanism of the nanowires was quantitatively revealed by photoelectron and photoionization spectroscopies of the Eu-COT species, together with supporting theoretical calculations. From these results, it is confirmed that growth processes extending the length of Eu-COT nanowires involve a series of elementary reactions in which efficient charge transfer occurs at the terminal reaction sites. In every elementary step, the reaction proceeds between one reactant having low ionization energy and the other reactant having high electron affinity, probably via a "harpoon" mechanism.

Original languageEnglish
Pages (from-to)9-12
Number of pages4
JournalJournal of Physical Chemistry A
Volume109
Issue number1
DOIs
Publication statusPublished - 2005 Jan 13

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Hosoya, N., Takegami, R., Suzumura, J. I., Yada, K., Koyasu, K., Miyajima, K., Mitsui, M., Knickelbein, M. B., Yabushita, S., & Nakajima, A. (2005). Lanthanide organometallic sandwich nanowires: Formation mechanism. Journal of Physical Chemistry A, 109(1), 9-12. https://doi.org/10.1021/jp0452103