Lipase-catalyzed transformation of poly(butylene adipate) and poly(butylene succinate) into repolymerizable cyclic oligomers

Sachiko Okajima, Reiko Kondo, Kazunobu Toshima, Shuichi Matsumura

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52 Citations (Scopus)

Abstract

The enzymatic degradation and repolymerization were carried out with the objectives of developing the chemical recycling of aliphatic polyester-type plastics, such as the poly(butylene adipate) (PBA), poly-(butylene succinate), and poly(butylene adipate-co-succinate) copolymers which are typical biodegradable plastics. They were degraded by lipase in an organic solvent solution containing a small amount of water to produce cyclic oligomers mainly consisting of the cyclic diester. The produced cyclic oligomer was readily repolymerized by lipase to produce a polyester having an equal or higher molecular weight compared to the parent polymer. As an example, PBA having an Mw of 22 000 was almost quantitatively transformed by lipase CA (Novozym 435) in water-containing toluene at 50 °C into the corresponding cyclic oligomers mainly consisting of dimers. Thus, the obtained oligomers were readily polymerized by lipase CA to produce the PBA with an Mw of 52 000.

Original languageEnglish
Pages (from-to)1514-1519
Number of pages6
JournalBiomacromolecules
Volume4
Issue number6
DOIs
Publication statusPublished - 2003 Nov 1

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ASJC Scopus subject areas

  • Bioengineering
  • Biomaterials
  • Polymers and Plastics
  • Materials Chemistry

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