Abstract
Lithium doped and undoped reactions for tin have been investigated in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing 0.1 M LiTFSA with some glymes. Lithium doped and undoped for tin were found to be possible in the ionic liquid electrolyte in both absence and presence of glymes. The interfacial resistance for lithium doped and undoped reactions in the ionic liquid electrolyte was decreased by addition of 0.2 M glymes probably due to the coordination of the glymes to Li+. It was suggested that the interfacial resistance is strongly affected by the coordination environment of Li+ in the ionic liquid electrolyte.
| Original language | English |
|---|---|
| Pages (from-to) | 6162-6166 |
| Number of pages | 5 |
| Journal | Journal of Power Sources |
| Volume | 195 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 2010 Sep 15 |
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Keywords
- Glyme
- Ionic liquid
- Rechargeable lithium battery
- Tin anode
ASJC Scopus subject areas
- Electrical and Electronic Engineering
- Energy Engineering and Power Technology
- Renewable Energy, Sustainability and the Environment
- Physical and Theoretical Chemistry
Cite this
Lithium dope and undope reactions for tin in an ionic liquid electrolyte with some glymes. / Katayama, Yasushi; Miyashita, Sodai; Miura, Takashi.
In: Journal of Power Sources, Vol. 195, No. 18, 15.09.2010, p. 6162-6166.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Lithium dope and undope reactions for tin in an ionic liquid electrolyte with some glymes
AU - Katayama, Yasushi
AU - Miyashita, Sodai
AU - Miura, Takashi
PY - 2010/9/15
Y1 - 2010/9/15
N2 - Lithium doped and undoped reactions for tin have been investigated in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing 0.1 M LiTFSA with some glymes. Lithium doped and undoped for tin were found to be possible in the ionic liquid electrolyte in both absence and presence of glymes. The interfacial resistance for lithium doped and undoped reactions in the ionic liquid electrolyte was decreased by addition of 0.2 M glymes probably due to the coordination of the glymes to Li+. It was suggested that the interfacial resistance is strongly affected by the coordination environment of Li+ in the ionic liquid electrolyte.
AB - Lithium doped and undoped reactions for tin have been investigated in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing 0.1 M LiTFSA with some glymes. Lithium doped and undoped for tin were found to be possible in the ionic liquid electrolyte in both absence and presence of glymes. The interfacial resistance for lithium doped and undoped reactions in the ionic liquid electrolyte was decreased by addition of 0.2 M glymes probably due to the coordination of the glymes to Li+. It was suggested that the interfacial resistance is strongly affected by the coordination environment of Li+ in the ionic liquid electrolyte.
KW - Glyme
KW - Ionic liquid
KW - Rechargeable lithium battery
KW - Tin anode
UR - http://www.scopus.com/inward/record.url?scp=77953136818&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77953136818&partnerID=8YFLogxK
U2 - 10.1016/j.jpowsour.2009.12.102
DO - 10.1016/j.jpowsour.2009.12.102
M3 - Article
AN - SCOPUS:77953136818
VL - 195
SP - 6162
EP - 6166
JO - Journal of Power Sources
JF - Journal of Power Sources
SN - 0378-7753
IS - 18
ER -