Lithium insertion behaviour of Li1+xV3O8 with different degrees of crystallinity

Jin Kawakita; Takahiro Kato; Yasushi Katayama; Takashi Miura; Tomiya Kishi

doi:10.1016/S0378-7753(99)00197-4

Lithium insertion behaviour of Li_1+xV₃O₈ with different degrees of crystallinity

Jin Kawakita, Takahiro Kato, Yasushi Katayama, Takashi Miura, Tomiya Kishi

Department of Applied Chemistry

Research output: Contribution to journal › Conference article › peer-review

61 Citations (Scopus)

Abstract

Lithium insertion behaviour of amorphous Li_1+xV₃O₈ was compared with that of poorly crystalline and highly crystalline LiV₃O₈. This oxide retained the amorphous state during discharge and charge cycle and exhibited electrochemical performance inferior to the crystalline one, i.e., smaller discharge capacity and lower cycle efficiency. The crystallinity of the crystalline Li_1+xV₃O₈ was one of the primary factors determining the rate of lithium insertion reaction.

Original language	English
Pages (from-to)	448-453
Number of pages	6
Journal	Journal of Power Sources
Volume	81-82
DOIs	https://doi.org/10.1016/S0378-7753(99)00197-4
Publication status	Published - 1999 Sept
Event	Proceedings of the 1998 Ninth International Meeting on Lithium Batteries - Edingburgh, United Kingdom Duration: 1998 Jul 12 → 1998 Jul 17

Keywords

Amorphous
Insertion
Lithium
Quenching
Vanadate

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/S0378-7753(99)00197-4

Cite this

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title = "Lithium insertion behaviour of Li1+xV3O8 with different degrees of crystallinity",

abstract = "Lithium insertion behaviour of amorphous Li1+xV3O8 was compared with that of poorly crystalline and highly crystalline LiV3O8. This oxide retained the amorphous state during discharge and charge cycle and exhibited electrochemical performance inferior to the crystalline one, i.e., smaller discharge capacity and lower cycle efficiency. The crystallinity of the crystalline Li1+xV3O8 was one of the primary factors determining the rate of lithium insertion reaction.",

keywords = "Amorphous, Insertion, Lithium, Quenching, Vanadate",

author = "Jin Kawakita and Takahiro Kato and Yasushi Katayama and Takashi Miura and Tomiya Kishi",

year = "1999",

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doi = "10.1016/S0378-7753(99)00197-4",

language = "English",

volume = "81-82",

pages = "448--453",

journal = "Journal of Power Sources",

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note = "Proceedings of the 1998 Ninth International Meeting on Lithium Batteries ; Conference date: 12-07-1998 Through 17-07-1998",

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TY - JOUR

T1 - Lithium insertion behaviour of Li1+xV3O8 with different degrees of crystallinity

AU - Kawakita, Jin

AU - Kato, Takahiro

AU - Katayama, Yasushi

AU - Miura, Takashi

AU - Kishi, Tomiya

PY - 1999/9

Y1 - 1999/9

N2 - Lithium insertion behaviour of amorphous Li1+xV3O8 was compared with that of poorly crystalline and highly crystalline LiV3O8. This oxide retained the amorphous state during discharge and charge cycle and exhibited electrochemical performance inferior to the crystalline one, i.e., smaller discharge capacity and lower cycle efficiency. The crystallinity of the crystalline Li1+xV3O8 was one of the primary factors determining the rate of lithium insertion reaction.

AB - Lithium insertion behaviour of amorphous Li1+xV3O8 was compared with that of poorly crystalline and highly crystalline LiV3O8. This oxide retained the amorphous state during discharge and charge cycle and exhibited electrochemical performance inferior to the crystalline one, i.e., smaller discharge capacity and lower cycle efficiency. The crystallinity of the crystalline Li1+xV3O8 was one of the primary factors determining the rate of lithium insertion reaction.

KW - Amorphous

KW - Insertion

KW - Lithium

KW - Quenching

KW - Vanadate

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DO - 10.1016/S0378-7753(99)00197-4

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VL - 81-82

SP - 448

EP - 453

JO - Journal of Power Sources

JF - Journal of Power Sources

T2 - Proceedings of the 1998 Ninth International Meeting on Lithium Batteries

Y2 - 12 July 1998 through 17 July 1998

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