Luminescent properties of dicyanoaurate(I) aggregates based on electrostatic assembly along poly(allylamine hydrochloride)

Toshiyuki Moriuchi; Kazuki Yoshii; Chiaki Katano; Toshikazu Hirao

doi:10.1016/j.tetlet.2010.05.087

Luminescent properties of dicyanoaurate(I) aggregates based on electrostatic assembly along poly(allylamine hydrochloride)

Toshiyuki Moriuchi, Kazuki Yoshii, Chiaki Katano, Toshikazu Hirao

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Poly(allylamine hydrochloride) (PAA) bearing positively charged side chains along the polymer chain was demonstrated to serve as a polymeric spatially aligned scaffold for aggregation and self-association of negatively charged [Au(CN)₂]^- through the electrostatic and aurophilic bonding interactions to afford the luminescent [Au(CN)₂]^- aggregates.

Original language	English
Pages (from-to)	4030-4032
Number of pages	3
Journal	Tetrahedron Letters
Volume	51
Issue number	31
DOIs	https://doi.org/10.1016/j.tetlet.2010.05.087
Publication status	Published - 2010 Aug 4

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Luminescent properties of dicyanoaurate(I) aggregates based on electrostatic assembly along poly(allylamine hydrochloride)",

abstract = "Poly(allylamine hydrochloride) (PAA) bearing positively charged side chains along the polymer chain was demonstrated to serve as a polymeric spatially aligned scaffold for aggregation and self-association of negatively charged [Au(CN)2]- through the electrostatic and aurophilic bonding interactions to afford the luminescent [Au(CN)2]- aggregates.",

author = "Toshiyuki Moriuchi and Kazuki Yoshii and Chiaki Katano and Toshikazu Hirao",

year = "2010",

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AU - Moriuchi, Toshiyuki

AU - Yoshii, Kazuki

AU - Katano, Chiaki

AU - Hirao, Toshikazu

PY - 2010/8/4

Y1 - 2010/8/4

N2 - Poly(allylamine hydrochloride) (PAA) bearing positively charged side chains along the polymer chain was demonstrated to serve as a polymeric spatially aligned scaffold for aggregation and self-association of negatively charged [Au(CN)2]- through the electrostatic and aurophilic bonding interactions to afford the luminescent [Au(CN)2]- aggregates.

AB - Poly(allylamine hydrochloride) (PAA) bearing positively charged side chains along the polymer chain was demonstrated to serve as a polymeric spatially aligned scaffold for aggregation and self-association of negatively charged [Au(CN)2]- through the electrostatic and aurophilic bonding interactions to afford the luminescent [Au(CN)2]- aggregates.

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