Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O

Yasuaki Einaga, Z. Z. Gu, Y. Kobayashi, O. Sato, T. Iyoda, F. Ambe, K. Hashimoto, A. Fujishima

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The electronic states of Fe atoms in Co[Fe(CN)5NH3]·xH2O were studied by means of 57Fe Mössbauer spectroscopy. The Mössbauer spectra of Co[Fe(CN)5NH3]·6H2O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.

Original languageEnglish
Pages (from-to)159-166
Number of pages8
JournalHyperfine Interactions
Volume116
Issue number1-4
Publication statusPublished - 1998
Externally publishedYes

Fingerprint

Magnetic relaxation
Atoms
magnetic relaxation
Electronic states
atoms
electron transfer
Spectroscopy
valence
Molecules
Electrons
Water
electronics
water
spectroscopy
molecules

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials
  • Nuclear and High Energy Physics

Cite this

Einaga, Y., Gu, Z. Z., Kobayashi, Y., Sato, O., Iyoda, T., Ambe, F., ... Fujishima, A. (1998). Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O. Hyperfine Interactions, 116(1-4), 159-166.

Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O. / Einaga, Yasuaki; Gu, Z. Z.; Kobayashi, Y.; Sato, O.; Iyoda, T.; Ambe, F.; Hashimoto, K.; Fujishima, A.

In: Hyperfine Interactions, Vol. 116, No. 1-4, 1998, p. 159-166.

Research output: Contribution to journalArticle

Einaga, Y, Gu, ZZ, Kobayashi, Y, Sato, O, Iyoda, T, Ambe, F, Hashimoto, K & Fujishima, A 1998, 'Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O', Hyperfine Interactions, vol. 116, no. 1-4, pp. 159-166.
Einaga Y, Gu ZZ, Kobayashi Y, Sato O, Iyoda T, Ambe F et al. Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O. Hyperfine Interactions. 1998;116(1-4):159-166.
Einaga, Yasuaki ; Gu, Z. Z. ; Kobayashi, Y. ; Sato, O. ; Iyoda, T. ; Ambe, F. ; Hashimoto, K. ; Fujishima, A. / Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O. In: Hyperfine Interactions. 1998 ; Vol. 116, No. 1-4. pp. 159-166.
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