Magnetic and electronic nature of layered manganese oxysulfide Sr 2CuMnO 3S

Yoichi Kamihara, Masanori Matoba, T. Kyomen, M. Itoh

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Abstract

We have synthesized and investigated the magnetic and electronic nature of layered manganese oxysulfide Sr 2CuMnO 3S which crystallizes in an unusual intergrowth structure with Cu 2S 2 and pyramidal MnO 5 layers separated by Sr ions. A Cu 2p x-ray photoemission spectroscopy (XPS) spectrum of Sr 2CuMnO 3S indicates that the Cu ion is in the monovalent state, or Cu +. This feature of the Mn 2p XPS spectrum of Sr 2CuMnO 3S is similar to that of the parent compound La 3+Mn 3+O 3 of colossal magnetoresistance materials. The MnO 5 cluster model analysis suggests that the electronic nature of the pyramidal MnO 5 layers belongs to a strongly correlated electron system, and the system is the so-called Mott insulator resulting from the strongly correlated electron nature. Magnetic susceptibility (χ) exhibits low-dimensional antiferromagnetic ordering of Mn 3+ in pyramidal MnO 5 layers. Fitting the χ data to Curie-Weiss law provides evidence of strong second neighbor Mn-Mn interaction.

Original languageEnglish
Pages (from-to)8864-8866
Number of pages3
JournalJournal of Applied Physics
Volume91
Issue number10 I
DOIs
Publication statusPublished - 2002 May 15

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manganese
photoelectric emission
electronics
Curie-Weiss law
spectroscopy
ions
electrons
x rays
insulators
magnetic permeability
interactions

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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Magnetic and electronic nature of layered manganese oxysulfide Sr 2CuMnO 3S. / Kamihara, Yoichi; Matoba, Masanori; Kyomen, T.; Itoh, M.

In: Journal of Applied Physics, Vol. 91, No. 10 I, 15.05.2002, p. 8864-8866.

Research output: Contribution to journalArticle

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N2 - We have synthesized and investigated the magnetic and electronic nature of layered manganese oxysulfide Sr 2CuMnO 3S which crystallizes in an unusual intergrowth structure with Cu 2S 2 and pyramidal MnO 5 layers separated by Sr ions. A Cu 2p x-ray photoemission spectroscopy (XPS) spectrum of Sr 2CuMnO 3S indicates that the Cu ion is in the monovalent state, or Cu +. This feature of the Mn 2p XPS spectrum of Sr 2CuMnO 3S is similar to that of the parent compound La 3+Mn 3+O 3 of colossal magnetoresistance materials. The MnO 5 cluster model analysis suggests that the electronic nature of the pyramidal MnO 5 layers belongs to a strongly correlated electron system, and the system is the so-called Mott insulator resulting from the strongly correlated electron nature. Magnetic susceptibility (χ) exhibits low-dimensional antiferromagnetic ordering of Mn 3+ in pyramidal MnO 5 layers. Fitting the χ data to Curie-Weiss law provides evidence of strong second neighbor Mn-Mn interaction.

AB - We have synthesized and investigated the magnetic and electronic nature of layered manganese oxysulfide Sr 2CuMnO 3S which crystallizes in an unusual intergrowth structure with Cu 2S 2 and pyramidal MnO 5 layers separated by Sr ions. A Cu 2p x-ray photoemission spectroscopy (XPS) spectrum of Sr 2CuMnO 3S indicates that the Cu ion is in the monovalent state, or Cu +. This feature of the Mn 2p XPS spectrum of Sr 2CuMnO 3S is similar to that of the parent compound La 3+Mn 3+O 3 of colossal magnetoresistance materials. The MnO 5 cluster model analysis suggests that the electronic nature of the pyramidal MnO 5 layers belongs to a strongly correlated electron system, and the system is the so-called Mott insulator resulting from the strongly correlated electron nature. Magnetic susceptibility (χ) exhibits low-dimensional antiferromagnetic ordering of Mn 3+ in pyramidal MnO 5 layers. Fitting the χ data to Curie-Weiss law provides evidence of strong second neighbor Mn-Mn interaction.

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