Magneto-structural correlations in dimeric copper(II) carboxylates

Shigeru Ohba, Michinobu Kato, Tadashi Tokii, Yoneichiro Muto, Omar W. Steward

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Abstract

For dimeric copper(II) carboxylates, the most important factor determining the strength of the spin superexchange interactions is the electronic structure of the carboxylato bridge. It also has been revealed that the trigonal bipyramidal deformation of the coordination geometry around the copper atoms, and the bending of the carboxylato bridge decrease the antiferromagnetic interactions.

Original languageEnglish
Pages (from-to)335-344
Number of pages10
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume233
Issue number1
DOIs
Publication statusPublished - 1993 Sep 1

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ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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