Magneto-structural correlations in dimeric copper(II) carboxylates

Shigeru Ohba, Michinobu Kato, Tadashi Tokii, Yoneichiro Muto, Omar W. Steward

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

For dimeric copper(II) carboxylates, the most important factor determining the strength of the spin superexchange interactions is the electronic structure of the carboxylato bridge. It also has been revealed that the trigonal bipyramidal deformation of the coordination geometry around the copper atoms, and the bending of the carboxylato bridge decrease the antiferromagnetic interactions.

Original languageEnglish
Pages (from-to)335-344
Number of pages10
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume233
Issue number1
DOIs
Publication statusPublished - 1993 Sep 1

Fingerprint

carboxylates
Copper
copper
Electronic structure
interactions
electronic structure
Atoms
Geometry
geometry
atoms

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Magneto-structural correlations in dimeric copper(II) carboxylates. / Ohba, Shigeru; Kato, Michinobu; Tokii, Tadashi; Muto, Yoneichiro; Steward, Omar W.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 233, No. 1, 01.09.1993, p. 335-344.

Research output: Contribution to journalArticle

Ohba, Shigeru ; Kato, Michinobu ; Tokii, Tadashi ; Muto, Yoneichiro ; Steward, Omar W. / Magneto-structural correlations in dimeric copper(II) carboxylates. In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 1993 ; Vol. 233, No. 1. pp. 335-344.
@article{1f2e191a69274bffbfaaaf2886a242c1,
title = "Magneto-structural correlations in dimeric copper(II) carboxylates",
abstract = "For dimeric copper(II) carboxylates, the most important factor determining the strength of the spin superexchange interactions is the electronic structure of the carboxylato bridge. It also has been revealed that the trigonal bipyramidal deformation of the coordination geometry around the copper atoms, and the bending of the carboxylato bridge decrease the antiferromagnetic interactions.",
author = "Shigeru Ohba and Michinobu Kato and Tadashi Tokii and Yoneichiro Muto and Steward, {Omar W.}",
year = "1993",
month = "9",
day = "1",
doi = "10.1080/10587259308054975",
language = "English",
volume = "233",
pages = "335--344",
journal = "Molecular Crystals and Liquid Crystals",
issn = "1542-1406",
publisher = "Taylor and Francis Ltd.",
number = "1",

}

TY - JOUR

T1 - Magneto-structural correlations in dimeric copper(II) carboxylates

AU - Ohba, Shigeru

AU - Kato, Michinobu

AU - Tokii, Tadashi

AU - Muto, Yoneichiro

AU - Steward, Omar W.

PY - 1993/9/1

Y1 - 1993/9/1

N2 - For dimeric copper(II) carboxylates, the most important factor determining the strength of the spin superexchange interactions is the electronic structure of the carboxylato bridge. It also has been revealed that the trigonal bipyramidal deformation of the coordination geometry around the copper atoms, and the bending of the carboxylato bridge decrease the antiferromagnetic interactions.

AB - For dimeric copper(II) carboxylates, the most important factor determining the strength of the spin superexchange interactions is the electronic structure of the carboxylato bridge. It also has been revealed that the trigonal bipyramidal deformation of the coordination geometry around the copper atoms, and the bending of the carboxylato bridge decrease the antiferromagnetic interactions.

UR - http://www.scopus.com/inward/record.url?scp=2742561172&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2742561172&partnerID=8YFLogxK

U2 - 10.1080/10587259308054975

DO - 10.1080/10587259308054975

M3 - Article

AN - SCOPUS:2742561172

VL - 233

SP - 335

EP - 344

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

SN - 1542-1406

IS - 1

ER -