Measurement of hydrogen-gas solubility and diffusivity in polymer electrolyte membrane by NMR method

Ryosuke Nagahisa, Daiki Kuriya, Kuniyasu Ogawa, Yasuyuki Takata, Kohei Ito

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Polymer electrolyte membrane (PEM) used for fuel cells and water electrolyzers is permeable to hydrogen gas, and the permeation causes to decrease the performance as electrochemical system. So, it is necessary to figure out the mechanism of hydrogen gas permeation and to develop the PEM that has lower gas permeability. In this study, we developed a new measurement system for hydrogen-gas solubility and diffusivity in PEM based on NMR method, which enables us to derive the solubility and diffusivity without assuming theoretical dissolution model. We apply the system to the dissolved hydrogen-gas in dry Nafion®117. The solubility obtained is proportional to ambient pressure and 2.9×10 -5 mol/cm 3@0.7MPa. The diffusivity is 3×10 -10 m 2/s. These values are discussed with comparing the values measured in conventional method.

Original languageEnglish
Title of host publicationECS Transactions
Pages1423-1430
Number of pages8
Volume41
Edition1
DOIs
Publication statusPublished - 2011
Event11th Polymer Electrolyte Fuel Cell Symposium, PEFC 11 - 220th ECS Meeting - Boston, MA, United States
Duration: 2011 Oct 92011 Oct 14

Other

Other11th Polymer Electrolyte Fuel Cell Symposium, PEFC 11 - 220th ECS Meeting
CountryUnited States
CityBoston, MA
Period11/10/911/10/14

Fingerprint

Solubility
Electrolytes
Nuclear magnetic resonance
Membranes
Hydrogen
Polymers
Gases
Permeation
Gas permeability
Fuel cells
Dissolution
Water

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Nagahisa, R., Kuriya, D., Ogawa, K., Takata, Y., & Ito, K. (2011). Measurement of hydrogen-gas solubility and diffusivity in polymer electrolyte membrane by NMR method. In ECS Transactions (1 ed., Vol. 41, pp. 1423-1430) https://doi.org/10.1149/1.3635673

Measurement of hydrogen-gas solubility and diffusivity in polymer electrolyte membrane by NMR method. / Nagahisa, Ryosuke; Kuriya, Daiki; Ogawa, Kuniyasu; Takata, Yasuyuki; Ito, Kohei.

ECS Transactions. Vol. 41 1. ed. 2011. p. 1423-1430.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Nagahisa, R, Kuriya, D, Ogawa, K, Takata, Y & Ito, K 2011, Measurement of hydrogen-gas solubility and diffusivity in polymer electrolyte membrane by NMR method. in ECS Transactions. 1 edn, vol. 41, pp. 1423-1430, 11th Polymer Electrolyte Fuel Cell Symposium, PEFC 11 - 220th ECS Meeting, Boston, MA, United States, 11/10/9. https://doi.org/10.1149/1.3635673
Nagahisa R, Kuriya D, Ogawa K, Takata Y, Ito K. Measurement of hydrogen-gas solubility and diffusivity in polymer electrolyte membrane by NMR method. In ECS Transactions. 1 ed. Vol. 41. 2011. p. 1423-1430 https://doi.org/10.1149/1.3635673
Nagahisa, Ryosuke ; Kuriya, Daiki ; Ogawa, Kuniyasu ; Takata, Yasuyuki ; Ito, Kohei. / Measurement of hydrogen-gas solubility and diffusivity in polymer electrolyte membrane by NMR method. ECS Transactions. Vol. 41 1. ed. 2011. pp. 1423-1430
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