Mechanical properties and chemical structures of biodegradable poly(butylene-succinate) for material reprocessing

Chiharu Kanemura, Shigeyuki Nakashima, Atsushi Hotta

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Poly(butylene-succinate) (PBS) was examined as a promising biodegradable and reprocessable material used for material recycling. The mechanical properties of PBS after immersed in water were investigated and it was found that the bending strength of PBS decreased as the immersion time and the immersion temperature increased due to the chemical degradation of PBS caused by hydrolysis. The chemically-degraded PBS was then reprocessed and re-examined to investigate the mechanical properties. An unusual increase both in the bending strength and in the molecular weight of PBS was observed. The increase was highly due to the autocatalytic action of PBS molecules during the reprocessing by esterification: dicarboxylic acids were produced through the low molecular PBS during the chemical degradation, which ended up in dehydration re-synthesis of PBS with higher molecular weight. The characteristic of the recovering behavior in the molecular weight of PBS after reprocessing could not be observed in poly(lactic acid) (PLA), one of the most-used biodegradable plastics.

Original languageEnglish
Pages (from-to)972-980
Number of pages9
JournalPolymer Degradation and Stability
Volume97
Issue number6
DOIs
Publication statusPublished - 2012 Jun

Fingerprint

butenes
molecular weight
Molecular weight
flexural strength
mechanical properties
Bending strength
Mechanical properties
submerging
degradation
Degradation
Dicarboxylic Acids
lactic acid
dicarboxylic acids
Esterification
Lactic acid
recycling
Dehydration
dehydration
hydrolysis
Recycling

Keywords

  • Biodegradation
  • Degradation
  • Material recycling
  • Poly(butylene-succinate)
  • Reprocessing

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry
  • Mechanics of Materials
  • Condensed Matter Physics

Cite this

Mechanical properties and chemical structures of biodegradable poly(butylene-succinate) for material reprocessing. / Kanemura, Chiharu; Nakashima, Shigeyuki; Hotta, Atsushi.

In: Polymer Degradation and Stability, Vol. 97, No. 6, 06.2012, p. 972-980.

Research output: Contribution to journalArticle

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