Abstract
The process of complex formation has been studied during milling a powder mixture of metallic Al and titania hydrogel, TiO2 · H2O. Solid state 27Al NMR and ESR are employed together with conventional x-ray diffractometry and thermal analyses. Al atoms partly changed from metallic to oxide state. 27Al NMR analyses indicate that two metallic Al states are allotted to distorted and undistorted lattices, while the other to AlOx units in the oxide state, where x is 4, 5, or 6. As detected by ESR, Ti4+ was partly reduced to Ti3+, suggesting a redox reaction during milling. A vigorous thermit reaction was detected during subsequent heating of the mixture after prolonged milling. These results indicate the formation of Al-O-Ti bonds during milling, leading to Al2TiO5 on subsequent heating.
| Original language | English |
|---|---|
| Pages (from-to) | 1305-1309 |
| Number of pages | 5 |
| Journal | Journal of Materials Research |
| Volume | 11 |
| Issue number | 5 |
| Publication status | Published - 1996 May |
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- Materials Science(all)
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Mechanisms of Al and titania hydrogel complex formation via a mechanical route. / Kojima, Yuumi; Isobe, Tetsuhiko; Senna, Mamoru; Shinohara, Takeshi; Ono, Sakai; Sumiyama, Kenji; Suzuki, Kenji.
In: Journal of Materials Research, Vol. 11, No. 5, 05.1996, p. 1305-1309.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Mechanisms of Al and titania hydrogel complex formation via a mechanical route
AU - Kojima, Yuumi
AU - Isobe, Tetsuhiko
AU - Senna, Mamoru
AU - Shinohara, Takeshi
AU - Ono, Sakai
AU - Sumiyama, Kenji
AU - Suzuki, Kenji
PY - 1996/5
Y1 - 1996/5
N2 - The process of complex formation has been studied during milling a powder mixture of metallic Al and titania hydrogel, TiO2 · H2O. Solid state 27Al NMR and ESR are employed together with conventional x-ray diffractometry and thermal analyses. Al atoms partly changed from metallic to oxide state. 27Al NMR analyses indicate that two metallic Al states are allotted to distorted and undistorted lattices, while the other to AlOx units in the oxide state, where x is 4, 5, or 6. As detected by ESR, Ti4+ was partly reduced to Ti3+, suggesting a redox reaction during milling. A vigorous thermit reaction was detected during subsequent heating of the mixture after prolonged milling. These results indicate the formation of Al-O-Ti bonds during milling, leading to Al2TiO5 on subsequent heating.
AB - The process of complex formation has been studied during milling a powder mixture of metallic Al and titania hydrogel, TiO2 · H2O. Solid state 27Al NMR and ESR are employed together with conventional x-ray diffractometry and thermal analyses. Al atoms partly changed from metallic to oxide state. 27Al NMR analyses indicate that two metallic Al states are allotted to distorted and undistorted lattices, while the other to AlOx units in the oxide state, where x is 4, 5, or 6. As detected by ESR, Ti4+ was partly reduced to Ti3+, suggesting a redox reaction during milling. A vigorous thermit reaction was detected during subsequent heating of the mixture after prolonged milling. These results indicate the formation of Al-O-Ti bonds during milling, leading to Al2TiO5 on subsequent heating.
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M3 - Article
VL - 11
SP - 1305
EP - 1309
JO - Journal of Materials Research
JF - Journal of Materials Research
SN - 0884-2914
IS - 5
ER -