Mechanisms of incipient chemical reaction between Ca(OH)2 and SiO2 under moderate mechanical stressing II

Examination of a radical mechanism by an EPR study

Tomoyuki Watanabe, Tetsuhiko Isobe, Mamoru Senna

Research output: Contribution to journal › Article

30 Citations (Scopus)

Abstract

An EPR spectroscopy was examined in detail in order to elucidate the role of mechanically induced radicals on the incipient mechanochemical reaction between Ca(OH)2 and SiO2. The specific radical species found on separately milled Ca(OH)2 and SiO2 disappeared in the case of mixed milling. O- radicals on Ca(OH)2 and E′centers on the SiO2 surface reacted during milling, leading to a precursor of complex oxide with Si-O-Ca bonding. Relative contribution of radical mechanism was compared with those of electron pairs to the complex formation of Si-O-Ca under mechanical stressing.

Original languageEnglish
Pages (from-to)291-296
Number of pages6
JournalJournal of Solid State Chemistry
Volume122
Issue number2
DOIs
Publication statusPublished - 1996 Mar

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Oxides
Paramagnetic resonance
Chemical reactions
chemical reactions
examination
Spectroscopy
Electrons
oxides
spectroscopy
electrons

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Mechanisms of incipient chemical reaction between Ca(OH)2 and SiO2 under moderate mechanical stressing II : Examination of a radical mechanism by an EPR study. / Watanabe, Tomoyuki; Isobe, Tetsuhiko; Senna, Mamoru.

In: Journal of Solid State Chemistry, Vol. 122, No. 2, 03.1996, p. 291-296.

Research output: Contribution to journal › Article

Watanabe, T, Isobe, T & Senna, M 1996, 'Mechanisms of incipient chemical reaction between Ca(OH)2 and SiO2 under moderate mechanical stressing II: Examination of a radical mechanism by an EPR study', Journal of Solid State Chemistry, vol. 122, no. 2, pp. 291-296. https://doi.org/10.1006/jssc.1996.0115
Watanabe T, Isobe T, Senna M. Mechanisms of incipient chemical reaction between Ca(OH)2 and SiO2 under moderate mechanical stressing II: Examination of a radical mechanism by an EPR study. Journal of Solid State Chemistry. 1996 Mar;122(2):291-296. https://doi.org/10.1006/jssc.1996.0115
Watanabe, Tomoyuki ; Isobe, Tetsuhiko ; Senna, Mamoru. / Mechanisms of incipient chemical reaction between Ca(OH)2 and SiO2 under moderate mechanical stressing II : Examination of a radical mechanism by an EPR study. In: Journal of Solid State Chemistry. 1996 ; Vol. 122, No. 2. pp. 291-296.
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