(meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate

Yoshiki Ohgo, Takashi Saitoh, Mikio Nakamura

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

In the title compound, (5, 10, 15, 20-tetraethylporphyrinato-κ4N)bis(tetrahydrofuran-O)iron(III) perchlorate, [Fe(C28H28N4)(C4H8O) 2]ClO4, the FeIII atom has a slightly distorted octahedral coordination. The porphyrin ring of the complex cation, which has twofold symmetry, has an S4-ruffled structure and the maximum deviation of the meso-carbon from the least-squares plane of the FeC20N4 core is 0.274 (3) Å. The average Fe-N bond distance is 2.006 (3) Å.

Original languageEnglish
Pages (from-to)1284-1286
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number8
Publication statusPublished - 1999 Aug 15

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Porphyrins
perchlorates
tetrahydrofuran
Least-Squares Analysis
porphyrins
Cations
Carbon
Iron
deviation
iron
cations
carbon
rings
symmetry
atoms
Atoms
perchlorate
iron perchlorate

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

(meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate. / Ohgo, Yoshiki; Saitoh, Takashi; Nakamura, Mikio.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 55, No. 8, 15.08.1999, p. 1284-1286.

Research output: Contribution to journalArticle

Ohgo, Yoshiki ; Saitoh, Takashi ; Nakamura, Mikio. / (meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate. In: Acta Crystallographica Section C: Crystal Structure Communications. 1999 ; Vol. 55, No. 8. pp. 1284-1286.
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