(meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate

Yoshiki Ohgo; Takashi Saitoh; Mikio Nakamura

doi:10.1107/S0108270199005429

(meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate

Yoshiki Ohgo, Takashi Saitoh, Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

In the title compound, (5, 10, 15, 20-tetraethylporphyrinato-κ⁴N)bis(tetrahydrofuran-O)iron(III) perchlorate, [Fe(C₂₈H₂₈N₄)(C₄H₈O) ₂]ClO₄, the Fe^III atom has a slightly distorted octahedral coordination. The porphyrin ring of the complex cation, which has twofold symmetry, has an S₄-ruffled structure and the maximum deviation of the meso-carbon from the least-squares plane of the FeC₂₀N₄ core is 0.274 (3) Å. The average Fe-N bond distance is 2.006 (3) Å.

Original language	English
Pages (from-to)	1284-1286
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Issue number	8
DOIs	https://doi.org/10.1107/S0108270199005429
Publication status	Published - 1999 Aug 15
Externally published	Yes

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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title = "(meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate",

abstract = "In the title compound, (5, 10, 15, 20-tetraethylporphyrinato-κ4N)bis(tetrahydrofuran-O)iron(III) perchlorate, [Fe(C28H28N4)(C4H8O) 2]ClO4, the FeIII atom has a slightly distorted octahedral coordination. The porphyrin ring of the complex cation, which has twofold symmetry, has an S4-ruffled structure and the maximum deviation of the meso-carbon from the least-squares plane of the FeC20N4 core is 0.274 (3) {\AA}. The average Fe-N bond distance is 2.006 (3) {\AA}.",

author = "Yoshiki Ohgo and Takashi Saitoh and Mikio Nakamura",

year = "1999",

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doi = "10.1107/S0108270199005429",

language = "English",

volume = "55",

pages = "1284--1286",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

number = "8",

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T1 - (meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate

AU - Ohgo, Yoshiki

AU - Saitoh, Takashi

AU - Nakamura, Mikio

PY - 1999/8/15

Y1 - 1999/8/15

N2 - In the title compound, (5, 10, 15, 20-tetraethylporphyrinato-κ4N)bis(tetrahydrofuran-O)iron(III) perchlorate, [Fe(C28H28N4)(C4H8O) 2]ClO4, the FeIII atom has a slightly distorted octahedral coordination. The porphyrin ring of the complex cation, which has twofold symmetry, has an S4-ruffled structure and the maximum deviation of the meso-carbon from the least-squares plane of the FeC20N4 core is 0.274 (3) Å. The average Fe-N bond distance is 2.006 (3) Å.

AB - In the title compound, (5, 10, 15, 20-tetraethylporphyrinato-κ4N)bis(tetrahydrofuran-O)iron(III) perchlorate, [Fe(C28H28N4)(C4H8O) 2]ClO4, the FeIII atom has a slightly distorted octahedral coordination. The porphyrin ring of the complex cation, which has twofold symmetry, has an S4-ruffled structure and the maximum deviation of the meso-carbon from the least-squares plane of the FeC20N4 core is 0.274 (3) Å. The average Fe-N bond distance is 2.006 (3) Å.

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ER -

(meso-Tetraethylporphyrinato)bis(tetrahydrofuran)iron(III) perchlorate

Abstract

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