Microfluidic synthesis and catalytic application of pvp-stabilized, ∼1 nm gold clusters

Hironori Tsunoyama; Nobuyuki Ichikuni; Tatsuya Tsukuda

doi:10.1021/la801372j

Microfluidic synthesis and catalytic application of pvp-stabilized, ∼1 nm gold clusters

Hironori Tsunoyama, Nobuyuki Ichikuni, Tatsuya Tsukuda

Research output: Contribution to journal › Article › peer-review

111 Citations (Scopus)

Abstract

Small PVP-stabilized gold clusters were successfully prepared by the homogeneous mixing of continuous flows of aqueous AuCl₄^- and BH₄^- in a micromixer. Spectroscopic characterization revealed that microfluidic synthesis could yield monodisperse Au:PVP clusters with an average diameter of ∼1 nm, which is smaller than clusters produced by conventional batch methods. These ∼1 nm Au:PVP clusters exhibited higher catalytic activity for the aerobic oxidation of p-hydroxybenzyl alcohol than did Au:PVP clusters prepared by batch methods.

Original language	English
Pages (from-to)	11327-11330
Number of pages	4
Journal	Langmuir
Volume	24
Issue number	20
DOIs	https://doi.org/10.1021/la801372j
Publication status	Published - 2008 Oct 21
Externally published	Yes

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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Microfluidic synthesis and catalytic application of pvp-stabilized, ∼1 nm gold clusters

Abstract

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