Microscale pin holders of β-Co(OH)2 and LiCoO2 having a single-crystalline feature

Keisuke Nakajima; Yuya Oaki; Hiroaki Imai

doi:10.1039/c3ce40688a

Microscale pin holders of β-Co(OH)₂ and LiCoO₂ having a single-crystalline feature

Keisuke Nakajima, Yuya Oaki, Hiroaki Imai

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Microscopic pin-holder structures of β-Co(OH)₂ having a feature of single crystal were synthesized through multistep crystal growth in an aqueous solution system. The hexagonal plates of the hydroxide were initially produced from an amorphous precursor. The parallel nanoscale pins of β-Co(OH)₂ were then grown on the basal plates in the progressive stage. The single-crystalline array of LiCoO₂ nanopins was obtained by topotactic transformation of the specifically shaped β-Co(OH) ₂ pin holders.

Original language	English
Pages (from-to)	6465-6468
Number of pages	4
Journal	CrystEngComm
Volume	15
Issue number	33
DOIs	https://doi.org/10.1039/c3ce40688a
Publication status	Published - 2013 Sept 7

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "Microscopic pin-holder structures of β-Co(OH)2 having a feature of single crystal were synthesized through multistep crystal growth in an aqueous solution system. The hexagonal plates of the hydroxide were initially produced from an amorphous precursor. The parallel nanoscale pins of β-Co(OH)2 were then grown on the basal plates in the progressive stage. The single-crystalline array of LiCoO2 nanopins was obtained by topotactic transformation of the specifically shaped β-Co(OH) 2 pin holders.",

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N2 - Microscopic pin-holder structures of β-Co(OH)2 having a feature of single crystal were synthesized through multistep crystal growth in an aqueous solution system. The hexagonal plates of the hydroxide were initially produced from an amorphous precursor. The parallel nanoscale pins of β-Co(OH)2 were then grown on the basal plates in the progressive stage. The single-crystalline array of LiCoO2 nanopins was obtained by topotactic transformation of the specifically shaped β-Co(OH) 2 pin holders.

AB - Microscopic pin-holder structures of β-Co(OH)2 having a feature of single crystal were synthesized through multistep crystal growth in an aqueous solution system. The hexagonal plates of the hydroxide were initially produced from an amorphous precursor. The parallel nanoscale pins of β-Co(OH)2 were then grown on the basal plates in the progressive stage. The single-crystalline array of LiCoO2 nanopins was obtained by topotactic transformation of the specifically shaped β-Co(OH) 2 pin holders.

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Microscale pin holders of β-Co(OH)₂ and LiCoO₂ having a single-crystalline feature

Abstract

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