Microwave effect on catalytic enantioselective Claisen rearrangement

Kazuya Nushiro, Satoshi Kikuchi, Tohru Yamada

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Catalytic enantioselective Claisen rearrangement was drastically enhanced under microwave irradiation conditions without any loss of the enantioselectivity. Based on Arrhenius plots it was revealed that enantioselectivity decreased as the internal reaction temperature increased. Therefore, this reaction acceleration would NOT be caused by only a simple thermal effect.

Original languageEnglish
Pages (from-to)8371-8373
Number of pages3
JournalChemical Communications
Volume49
Issue number75
DOIs
Publication statusPublished - 2013 Sep 28

Fingerprint

Enantioselectivity
Microwaves
Arrhenius plots
Microwave irradiation
Thermal effects
Temperature

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Microwave effect on catalytic enantioselective Claisen rearrangement. / Nushiro, Kazuya; Kikuchi, Satoshi; Yamada, Tohru.

In: Chemical Communications, Vol. 49, No. 75, 28.09.2013, p. 8371-8373.

Research output: Contribution to journalArticle

Nushiro, Kazuya ; Kikuchi, Satoshi ; Yamada, Tohru. / Microwave effect on catalytic enantioselective Claisen rearrangement. In: Chemical Communications. 2013 ; Vol. 49, No. 75. pp. 8371-8373.
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