Microwave enhancement on ring-closing metathesis of macrocyclic bisazole

Taichi Sawada; Shigeki Tashima; Kodai Saito; Tohru Yamada

doi:10.1246/cl.160982

Microwave enhancement on ring-closing metathesis of macrocyclic bisazole

Taichi Sawada, Shigeki Tashima, Kodai Saito, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Microwave irradiation was applied to a sterically demanding ring-closing metathesis catalyzed by a second-generation Grubbs catalyst. Under strict temperature control, reaction acceleration by microwave irradiation was observed. The observed acceleration effect was estimated to be equivalent to a rising temperature of 2.5-5°C range under conventional heating conditions.

Original language	English
Pages (from-to)	274-276
Number of pages	3
Journal	Chemistry Letters
Volume	46
Issue number	2
DOIs	https://doi.org/10.1246/cl.160982
Publication status	Published - 2017

Keywords

Microwave specific effect
Reaction acceleration
Ring-closing metathesis

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.160982

Cite this

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title = "Microwave enhancement on ring-closing metathesis of macrocyclic bisazole",

abstract = "Microwave irradiation was applied to a sterically demanding ring-closing metathesis catalyzed by a second-generation Grubbs catalyst. Under strict temperature control, reaction acceleration by microwave irradiation was observed. The observed acceleration effect was estimated to be equivalent to a rising temperature of 2.5-5°C range under conventional heating conditions.",

keywords = "Microwave specific effect, Reaction acceleration, Ring-closing metathesis",

author = "Taichi Sawada and Shigeki Tashima and Kodai Saito and Tohru Yamada",

note = "Publisher Copyright: {\textcopyright} 2017 The Chemical Society of Japan.",

year = "2017",

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T1 - Microwave enhancement on ring-closing metathesis of macrocyclic bisazole

AU - Sawada, Taichi

AU - Tashima, Shigeki

AU - Saito, Kodai

AU - Yamada, Tohru

PY - 2017

Y1 - 2017

N2 - Microwave irradiation was applied to a sterically demanding ring-closing metathesis catalyzed by a second-generation Grubbs catalyst. Under strict temperature control, reaction acceleration by microwave irradiation was observed. The observed acceleration effect was estimated to be equivalent to a rising temperature of 2.5-5°C range under conventional heating conditions.

AB - Microwave irradiation was applied to a sterically demanding ring-closing metathesis catalyzed by a second-generation Grubbs catalyst. Under strict temperature control, reaction acceleration by microwave irradiation was observed. The observed acceleration effect was estimated to be equivalent to a rising temperature of 2.5-5°C range under conventional heating conditions.

KW - Microwave specific effect

KW - Reaction acceleration

KW - Ring-closing metathesis

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JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

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ER -

Microwave enhancement on ring-closing metathesis of macrocyclic bisazole

Abstract

Keywords

ASJC Scopus subject areas

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