Microwave enhancement on ring-closing metathesis of macrocyclic bisazole

Taichi Sawada; Shigeki Tashima; Kodai Saito; Tohru Yamada

doi:10.1246/cl.160982

Microwave enhancement on ring-closing metathesis of macrocyclic bisazole

Taichi Sawada, Shigeki Tashima, Kodai Saito, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

Microwave irradiation was applied to a sterically demanding ring-closing metathesis catalyzed by a second-generation Grubbs catalyst. Under strict temperature control, reaction acceleration by microwave irradiation was observed. The observed acceleration effect was estimated to be equivalent to a rising temperature of 2.5-5°C range under conventional heating conditions.

Original language	English
Pages (from-to)	274-276
Number of pages	3
Journal	Chemistry Letters
Volume	46
Issue number	2
DOIs	https://doi.org/10.1246/cl.160982
Publication status	Published - 2017

Keywords

Microwave specific effect
Reaction acceleration
Ring-closing metathesis

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.160982

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Sawada, T., Tashima, S., Saito, K., & Yamada, T. (2017). Microwave enhancement on ring-closing metathesis of macrocyclic bisazole. Chemistry Letters, 46(2), 274-276. https://doi.org/10.1246/cl.160982

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abstract = "Microwave irradiation was applied to a sterically demanding ring-closing metathesis catalyzed by a second-generation Grubbs catalyst. Under strict temperature control, reaction acceleration by microwave irradiation was observed. The observed acceleration effect was estimated to be equivalent to a rising temperature of 2.5-5°C range under conventional heating conditions.",

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