Microwave specific effect on catalytic enantioselective reactions

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The microwave specific effect was investigated on the catalytic enantioselective reactions; atropo-enantiveselective ring-opening reaction of biaryl lactones and enantioselective Claisen rearrangement reaction. These reactions were efficiently enhanced with microwave irradiation under reaction temperature control, thought any loss of the enantioselectivities were not detected. It was also found that the racemization rate of the atropo-optically active biaryl lactone was enhanced by microwave irradiation. As these observations could not be explained by the simple thermal effect, microwave specific effect should be considered.

Original languageEnglish
Title of host publication2018 Asia-Pacific Microwave Conference, APMC 2018 - Proceedings
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages1627-1629
Number of pages3
ISBN (Electronic)9784902339451
DOIs
Publication statusPublished - 2019 Jan 16
Event30th Asia-Pacific Microwave Conference, APMC 2018 - Kyoto, Japan
Duration: 2018 Nov 62018 Nov 9

Publication series

NameAsia-Pacific Microwave Conference Proceedings, APMC
Volume2018-November

Conference

Conference30th Asia-Pacific Microwave Conference, APMC 2018
CountryJapan
CityKyoto
Period18/11/618/11/9

Fingerprint

Microwave irradiation
Microwaves
Enantioselectivity
Temperature control
Thermal effects

Keywords

  • Asymmetric
  • Catalysis
  • Enantioselective
  • Rearrangement
  • Reduction
  • Thermal effect

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

Cite this

Yamada, T. (2019). Microwave specific effect on catalytic enantioselective reactions. In 2018 Asia-Pacific Microwave Conference, APMC 2018 - Proceedings (pp. 1627-1629). [8617203] (Asia-Pacific Microwave Conference Proceedings, APMC; Vol. 2018-November). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.23919/APMC.2018.8617203

Microwave specific effect on catalytic enantioselective reactions. / Yamada, Tohru.

2018 Asia-Pacific Microwave Conference, APMC 2018 - Proceedings. Institute of Electrical and Electronics Engineers Inc., 2019. p. 1627-1629 8617203 (Asia-Pacific Microwave Conference Proceedings, APMC; Vol. 2018-November).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Yamada, T 2019, Microwave specific effect on catalytic enantioselective reactions. in 2018 Asia-Pacific Microwave Conference, APMC 2018 - Proceedings., 8617203, Asia-Pacific Microwave Conference Proceedings, APMC, vol. 2018-November, Institute of Electrical and Electronics Engineers Inc., pp. 1627-1629, 30th Asia-Pacific Microwave Conference, APMC 2018, Kyoto, Japan, 18/11/6. https://doi.org/10.23919/APMC.2018.8617203
Yamada T. Microwave specific effect on catalytic enantioselective reactions. In 2018 Asia-Pacific Microwave Conference, APMC 2018 - Proceedings. Institute of Electrical and Electronics Engineers Inc. 2019. p. 1627-1629. 8617203. (Asia-Pacific Microwave Conference Proceedings, APMC). https://doi.org/10.23919/APMC.2018.8617203
Yamada, Tohru. / Microwave specific effect on catalytic enantioselective reactions. 2018 Asia-Pacific Microwave Conference, APMC 2018 - Proceedings. Institute of Electrical and Electronics Engineers Inc., 2019. pp. 1627-1629 (Asia-Pacific Microwave Conference Proceedings, APMC).
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