Molecular complexes of anionic porphyrin and anionic aromatics

Toshinori Sato, Teiichiro Ogawa, Koji Kano

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Absorption and fluorescence emission spectra indicated that an anionic porphyrin, 5-phenyl-10,15,20-tris(p-sulfonatophenyl)porphine (TPPS3-), in water formed ground-state complexes with various anionic aromatics. The thermodynamic parameters (ΔH and ΔS) for complexation suggested that a van der Waals interaction is the predominant binding force and a hydrophobic interaction assists the stabilization of the complexes.

Original languageEnglish
Pages (from-to)3678-3682
Number of pages5
JournalJournal of Physical Chemistry
Volume88
Issue number16
DOIs
Publication statusPublished - 1984

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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