Molecular design, characterization, and application of multi-information dyes for multi-dimensional optical chemical sensing. Molecular design concepts of the dyes and their fundamental spectral characteristics

Hideaki Hisamoto, Hajime Tohma, Toshiki Yamada, Ki Ichiro Yamauchi, Dwi Siswanta, Naoki Yoshioka, Koji Suzuki

Research output: Contribution to journalArticlepeer-review

57 Citations (Scopus)

Abstract

The molecular design of multi-functional dyes, called 'multi-information dyes' (MIDs), and their application to several methods of optical chemical sensing were proposed. The concepts for the molecular design of the dyes were as follows: (1) the introduction of multiple (both positive and negative) charges on both ends of the large conjugated π-electron system of the dye molecule, so that the dye interacts with many chemical species or environments; (2) the introduction of different substitution (electron-donating or electron-accepting) groups in the conjugated π-electron system of the dye molecule, so that the dye has a different pK(a) and solvatochromic property; and (3) the introduction of an immobilization site in the dye molecule, so that the dye can be easily prepared as a sensing probe.Based on these concepts, sixteen kinds of dyes were synthesized, all being of the merocyanine type. The basic color-change characteristics of the MIDs were evaluated with a homogeneous system and a solvent extraction two-phase system. Some of these dyes (e.g., KD-M5) offered two-dimensional sensing information for sensing the water content in organic solvents, in which the absorbance maximum wavelength (λ(max)) shift and absorbance change were both utilized as the detecting signals.From these results, the MIDs developed in this study have several possibilities for analytical applications in optical chemical sensing such as pH sensing, ion sensing, neutral molecule sensing, and water content-sensing in organic solvents. Copyright (C) 1998 Elsevier Science B.V.

Original languageEnglish
Pages (from-to)271-289
Number of pages19
JournalAnalytica Chimica Acta
Volume373
Issue number2-3
DOIs
Publication statusPublished - 1998 Nov 11

Keywords

  • Alcohol sensor
  • Functional dye
  • Ion sensor
  • Optical sensor
  • Optode
  • Solvatochromism
  • Water-content sensor
  • pH sensor

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy

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