Mono-aryloxy or mono-alkoxy zirconium complexes/methylaluminoxane catalyst system in ethylene polymerization

Makoto Mitani, Kunihiro Oouchi, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Mono-aryloxy zirconium complexes 1-6 or mono-alkoxy zirconium complexes 7-10 were prepared and the ethylene polymerization was carried out in the presence of these complexes/methylaluminoxane. Steric factor of the aryloxy and alkoxy ligands in the complexes remarkably influenced on activity of ethylene polymerization.

Original languageEnglish
Pages (from-to)199-202
Number of pages4
JournalPolymer Bulletin
Volume34
Issue number2
DOIs
Publication statusPublished - 1995 Feb
Externally publishedYes

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Zirconium
Ethylene
ethylene
polymerization
Polymerization
catalysts
Catalysts
Ligands
ligands
alkoxyl radical

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Mono-aryloxy or mono-alkoxy zirconium complexes/methylaluminoxane catalyst system in ethylene polymerization. / Mitani, Makoto; Oouchi, Kunihiro; Hayakawa, Michiya; Yamada, Tohru; Mukaiyama, Teruaki.

In: Polymer Bulletin, Vol. 34, No. 2, 02.1995, p. 199-202.

Research output: Contribution to journalArticle

Mitani, Makoto ; Oouchi, Kunihiro ; Hayakawa, Michiya ; Yamada, Tohru ; Mukaiyama, Teruaki. / Mono-aryloxy or mono-alkoxy zirconium complexes/methylaluminoxane catalyst system in ethylene polymerization. In: Polymer Bulletin. 1995 ; Vol. 34, No. 2. pp. 199-202.
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