Monomeric and polymeric structures of oxovanadium(IV) complexes with Schiff base ligands derived from ( R,R )-2,4-pentanediamine: Synthesis and crystal structure

Masanobu Tsuchimoto, Ryuichi Kasahara, Kiyohiko Nakajima, Masaaki Kojima, Shigeru Ohba

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

New tetradentate Schiff base-oxovanadium(IV) complexes which have electron donating or withdrawing groups at the 5-position of the salicylaldehyde moieties, [VO{Xsal-(R,R)-2,4-ptn}] (H2{Xsal-(R,R)-2,4-ptn}: N,N′-di-Xsalicylidene-(R,R)-2,4-pentanediamine; X=5-MeO (methoxy), 5-Br, and 5-NO2) were prepared. The structures and redox potentials for the V(V)/V(IV) couple of the complexes were compared with those of other [VO{Xsal-(R,R)-2,4-ptn}] (X=3-EtO (ethoxy), 3-MeO, and H). The 5-MeO substituted complex which has electron donating groups at the 5-position of the salicylaldehyde moieties forms a monomeric structure in the solid state. The 3-EtO substituted complex has both monomeric and polymeric structures. On the other hand, the other [VO{Xsal-(R,R)-2,4-ptn}] (X=H, 3-MeO, 5-Br, 5-NO2) complexes have only polymeric structures. X-ray crystal structure analysis of [VO{5-MeOsal-(R,R)-2,4-ptn}]CH3OH (1) was carried out. Complex 1 has a monomeric five-coordinate square-pyramidal structure. The six-membered N-N chelate ring forms a distorted flattened boat form with two methyl groups in the axial positions.

Original languageEnglish
Pages (from-to)3035-3039
Number of pages5
JournalPolyhedron
Volume18
Issue number23
Publication statusPublished - 1999 Oct 8

Fingerprint

Schiff Bases
imines
Crystal structure
Ligands
Electrons
ligands
crystal structure
Ships
Boats
synthesis
Oxidation-Reduction
X-Rays
boats
chelates
X rays
electrons
solid state
rings
oxovanadium IV
salicylaldehyde

Keywords

  • Electronic influence of substituents
  • Monomeric structures
  • Oxovanadium(IV) complexes
  • Polymeric structures

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Monomeric and polymeric structures of oxovanadium(IV) complexes with Schiff base ligands derived from ( R,R )-2,4-pentanediamine : Synthesis and crystal structure. / Tsuchimoto, Masanobu; Kasahara, Ryuichi; Nakajima, Kiyohiko; Kojima, Masaaki; Ohba, Shigeru.

In: Polyhedron, Vol. 18, No. 23, 08.10.1999, p. 3035-3039.

Research output: Contribution to journalArticle

Tsuchimoto, Masanobu ; Kasahara, Ryuichi ; Nakajima, Kiyohiko ; Kojima, Masaaki ; Ohba, Shigeru. / Monomeric and polymeric structures of oxovanadium(IV) complexes with Schiff base ligands derived from ( R,R )-2,4-pentanediamine : Synthesis and crystal structure. In: Polyhedron. 1999 ; Vol. 18, No. 23. pp. 3035-3039.
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abstract = "New tetradentate Schiff base-oxovanadium(IV) complexes which have electron donating or withdrawing groups at the 5-position of the salicylaldehyde moieties, [VO{Xsal-(R,R)-2,4-ptn}] (H2{Xsal-(R,R)-2,4-ptn}: N,N′-di-Xsalicylidene-(R,R)-2,4-pentanediamine; X=5-MeO (methoxy), 5-Br, and 5-NO2) were prepared. The structures and redox potentials for the V(V)/V(IV) couple of the complexes were compared with those of other [VO{Xsal-(R,R)-2,4-ptn}] (X=3-EtO (ethoxy), 3-MeO, and H). The 5-MeO substituted complex which has electron donating groups at the 5-position of the salicylaldehyde moieties forms a monomeric structure in the solid state. The 3-EtO substituted complex has both monomeric and polymeric structures. On the other hand, the other [VO{Xsal-(R,R)-2,4-ptn}] (X=H, 3-MeO, 5-Br, 5-NO2) complexes have only polymeric structures. X-ray crystal structure analysis of [VO{5-MeOsal-(R,R)-2,4-ptn}]CH3OH (1) was carried out. Complex 1 has a monomeric five-coordinate square-pyramidal structure. The six-membered N-N chelate ring forms a distorted flattened boat form with two methyl groups in the axial positions.",
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T1 - Monomeric and polymeric structures of oxovanadium(IV) complexes with Schiff base ligands derived from ( R,R )-2,4-pentanediamine

T2 - Synthesis and crystal structure

AU - Tsuchimoto, Masanobu

AU - Kasahara, Ryuichi

AU - Nakajima, Kiyohiko

AU - Kojima, Masaaki

AU - Ohba, Shigeru

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N2 - New tetradentate Schiff base-oxovanadium(IV) complexes which have electron donating or withdrawing groups at the 5-position of the salicylaldehyde moieties, [VO{Xsal-(R,R)-2,4-ptn}] (H2{Xsal-(R,R)-2,4-ptn}: N,N′-di-Xsalicylidene-(R,R)-2,4-pentanediamine; X=5-MeO (methoxy), 5-Br, and 5-NO2) were prepared. The structures and redox potentials for the V(V)/V(IV) couple of the complexes were compared with those of other [VO{Xsal-(R,R)-2,4-ptn}] (X=3-EtO (ethoxy), 3-MeO, and H). The 5-MeO substituted complex which has electron donating groups at the 5-position of the salicylaldehyde moieties forms a monomeric structure in the solid state. The 3-EtO substituted complex has both monomeric and polymeric structures. On the other hand, the other [VO{Xsal-(R,R)-2,4-ptn}] (X=H, 3-MeO, 5-Br, 5-NO2) complexes have only polymeric structures. X-ray crystal structure analysis of [VO{5-MeOsal-(R,R)-2,4-ptn}]CH3OH (1) was carried out. Complex 1 has a monomeric five-coordinate square-pyramidal structure. The six-membered N-N chelate ring forms a distorted flattened boat form with two methyl groups in the axial positions.

AB - New tetradentate Schiff base-oxovanadium(IV) complexes which have electron donating or withdrawing groups at the 5-position of the salicylaldehyde moieties, [VO{Xsal-(R,R)-2,4-ptn}] (H2{Xsal-(R,R)-2,4-ptn}: N,N′-di-Xsalicylidene-(R,R)-2,4-pentanediamine; X=5-MeO (methoxy), 5-Br, and 5-NO2) were prepared. The structures and redox potentials for the V(V)/V(IV) couple of the complexes were compared with those of other [VO{Xsal-(R,R)-2,4-ptn}] (X=3-EtO (ethoxy), 3-MeO, and H). The 5-MeO substituted complex which has electron donating groups at the 5-position of the salicylaldehyde moieties forms a monomeric structure in the solid state. The 3-EtO substituted complex has both monomeric and polymeric structures. On the other hand, the other [VO{Xsal-(R,R)-2,4-ptn}] (X=H, 3-MeO, 5-Br, 5-NO2) complexes have only polymeric structures. X-ray crystal structure analysis of [VO{5-MeOsal-(R,R)-2,4-ptn}]CH3OH (1) was carried out. Complex 1 has a monomeric five-coordinate square-pyramidal structure. The six-membered N-N chelate ring forms a distorted flattened boat form with two methyl groups in the axial positions.

KW - Electronic influence of substituents

KW - Monomeric structures

KW - Oxovanadium(IV) complexes

KW - Polymeric structures

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