Morphology and mechanical property of quenched poly(L-lactide)/N,N-dimethylacetamide gels

Shunya Inukai, Naruki Kurokawa, Fuyuaki Endo, Tomoki Maeda, Atsushi Hotta

Research output: Contribution to journalArticlepeer-review

Abstract

Mechanically tough poly(L-lactide) (PLLA)/N,N-dimethylacetamide (DMAc) gels by rapid quenching using liquid nitrogen (LN) were synthesized. PLLA/DMAc solution at 110 °C was cooled at room temperature (PLLA-RT), or quenched by LN before keeping at RT (PLLA-LN). PLLA-RT with the PLLA concentrations of 5, 8, and 11 wt% did not form gel, while PLLA-RT with 14 and 17 wt% could form brittle gel exhibiting coarse structures. In contrast, PLLA-LN could form stable gel regardless of the PLLA concentration. The storage modulus of the gel with the PLLA concentration of 17 wt% increased from 78.7 kPa (PLLA-RT) to 563.7 kPa (PLLA-LN) at the strain of 0.1%. From the structural analysis, PLLA-RT formed spherulites (100–200 μm in diameter), whereas PLLA-LN formed relatively uniform network structures with continuous microporous skeletons without spherulites. The structural changes significantly contributed to the formation of stable, re-moldable, biodegradable, and biocompatible physical gels with ecofriendly and enhanced mechanical properties.

Original languageEnglish
Article number124581
JournalPolymer
Volume242
DOIs
Publication statusPublished - 2022 Mar 1

Keywords

  • Mechanical property
  • Physical gel
  • Poly(L-lactide)

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'Morphology and mechanical property of quenched poly(L-lactide)/N,N-dimethylacetamide gels'. Together they form a unique fingerprint.

Cite this