Mossbauer study on photochemistry of ferrocene isolated in low- temperature matrix

Yasuaki Einaga, Y. Yamada, T. Tominaga

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Abstract

Unstable novel species produced by photolysis of ferrocene (Cp2Fe) isolated in low-temperature matrix were studied by means of the 57Fe Mossbauer spectroscopy. On the UV-irradiation of 57Fe-enriched ferrocene co-condensed with CCl2 in low-temperature N2 matrix (20 K), unknown high spin ferrous species (I.S. = 0.90 ± 0.02 mm/s), Q.S. = 1.94 ± 0.02 mm/s) were produced as well as ferricinium ion [Cp2Fe]+ (I.S. = 0.52 ± 0.01 mm/s, Q.S. = 0.0 mm/s). On the annealing, these photoproducts disappeared to reform ferrocene by the reverse reaction in the matrix. The mechanisms of the photochemical reaction were discussed.

Original languageEnglish
Pages (from-to)97-100
Number of pages4
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume218
Issue number1
DOIs
Publication statusPublished - 1997
Externally publishedYes

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Inorganic Chemistry
  • Nuclear Energy and Engineering

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