Abstract
Vanadium (V)-C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m) = (1,1), (1,2) (2,3), (3-4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure V atom and C60 are alternatively piled up. The ionization energy and the reactivity of the dumbbell clusters toward O2 and CO show V1(C60)2 takes a structure of V1(η6 -C60)2.
| Original language | English |
|---|---|
| Pages (from-to) | 6491-6494 |
| Number of pages | 4 |
| Journal | Journal of Chemical Physics |
| Volume | 107 |
| Issue number | 16 |
| Publication status | Published - 1997 Oct 22 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Multiple dumbbell structures of vanadium-C60 clusters. / Nakajima, Atsushi; Nagao, Satoshi; Takeda, Hiroaki; Kurikawa, Tsuyoshi; Kaya, Koji.
In: Journal of Chemical Physics, Vol. 107, No. 16, 22.10.1997, p. 6491-6494.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Multiple dumbbell structures of vanadium-C60 clusters
AU - Nakajima, Atsushi
AU - Nagao, Satoshi
AU - Takeda, Hiroaki
AU - Kurikawa, Tsuyoshi
AU - Kaya, Koji
PY - 1997/10/22
Y1 - 1997/10/22
N2 - Vanadium (V)-C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m) = (1,1), (1,2) (2,3), (3-4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure V atom and C60 are alternatively piled up. The ionization energy and the reactivity of the dumbbell clusters toward O2 and CO show V1(C60)2 takes a structure of V1(η6 -C60)2.
AB - Vanadium (V)-C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m) = (1,1), (1,2) (2,3), (3-4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure V atom and C60 are alternatively piled up. The ionization energy and the reactivity of the dumbbell clusters toward O2 and CO show V1(C60)2 takes a structure of V1(η6 -C60)2.
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M3 - Article
AN - SCOPUS:0000221078
VL - 107
SP - 6491
EP - 6494
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 16
ER -