Abstract
Spatial recoil anisotropy for a metal-ion-ligand complex after a single photoexcitation process of Mg+ -ICH3 by linearly polarized light was investigated. A density functional theory (DFT) was applied for a geometry optimization. Natural population analysis and configuration interaction singles (CIS) calculations were performed for estimating the charge distribution in the parent ion and the excitation energies from the ground state. It was found that the fragment ions were formed along dissociative potential surfaces which were crossed by the initially excited states, in a much faster process than the rotational period of the complex.
| Original language | English |
|---|---|
| Journal | Physical Review Letters |
| Volume | 93 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - 2004 Nov 5 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
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Multiple photofragmentation pathways with different recoil anisotropy from a metal-ion-ligand complex. / Misaizu, Fuminori; Furuya, Ari; Tsunoyama, Hironori; Ohno, Koichi.
In: Physical Review Letters, Vol. 93, No. 19, 05.11.2004.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Multiple photofragmentation pathways with different recoil anisotropy from a metal-ion-ligand complex
AU - Misaizu, Fuminori
AU - Furuya, Ari
AU - Tsunoyama, Hironori
AU - Ohno, Koichi
PY - 2004/11/5
Y1 - 2004/11/5
N2 - Spatial recoil anisotropy for a metal-ion-ligand complex after a single photoexcitation process of Mg+ -ICH3 by linearly polarized light was investigated. A density functional theory (DFT) was applied for a geometry optimization. Natural population analysis and configuration interaction singles (CIS) calculations were performed for estimating the charge distribution in the parent ion and the excitation energies from the ground state. It was found that the fragment ions were formed along dissociative potential surfaces which were crossed by the initially excited states, in a much faster process than the rotational period of the complex.
AB - Spatial recoil anisotropy for a metal-ion-ligand complex after a single photoexcitation process of Mg+ -ICH3 by linearly polarized light was investigated. A density functional theory (DFT) was applied for a geometry optimization. Natural population analysis and configuration interaction singles (CIS) calculations were performed for estimating the charge distribution in the parent ion and the excitation energies from the ground state. It was found that the fragment ions were formed along dissociative potential surfaces which were crossed by the initially excited states, in a much faster process than the rotational period of the complex.
UR - http://www.scopus.com/inward/record.url?scp=19744371871&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=19744371871&partnerID=8YFLogxK
U2 - 10.1103/PhysRevLett.93.193401
DO - 10.1103/PhysRevLett.93.193401
M3 - Article
C2 - 15600832
AN - SCOPUS:19744371871
VL - 93
JO - Physical Review Letters
JF - Physical Review Letters
SN - 0031-9007
IS - 19
ER -