N-(Isopropyl)norbornane-endo-2,3-dicarboximide

Ryouko Yoshihara, Hiroyuki Hosomi, Hiromu Aoyama, Shigeru Ohba

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The geometry of the title molecule, N-isopropylbicyclo-[2.2.1]heptane-endo-2,3-dicarboximide, C12H17NO2, has been confirmed as the endo conformation. The orientation of the isopropyl (iPr) group relative to the succinimide moiety is a little unsymmetric and the iPr group rotates ca 6 ° around the N - C bond from the perpendicular configuration. This causes the stereoselectivity of the photoreaction in the solid state. The diastereoexcess of the ring expansion products indicates that the carbonyl-O atom predominantly abstracts the nearest γ-hydrogen in the molecule.

Original languageEnglish
Pages (from-to)960-962
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number6
DOIs
Publication statusPublished - 1999 Jun 15

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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