New class of catalysts for alternating copolymerization of alkylene oxide and carbon dioxide

Atsushi Okada; Satoshi Kikuchi; Koji Nakano; Kiyoshi Nishioka; Kyoko Nozaki; Tohru Yamada

doi:10.1246/cl.2010.1066

New class of catalysts for alternating copolymerization of alkylene oxide and carbon dioxide

Atsushi Okada, Satoshi Kikuchi, Koji Nakano, Kiyoshi Nishioka, Kyoko Nozaki, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Di(ketoiminato)cobalt complexes have been employed for the alternating copolymerization of alkylene oxide and carbon dioxide. These complexes exhibited not only good catalytic activity for polycarbonate synthesis, but also an excellent selectivity for the formation of carbonate linkages without any ether linkage in the reaction of several alkylene oxides, especially for ethylene oxide.

Original language	English
Pages (from-to)	1066-1068
Number of pages	3
Journal	Chemistry Letters
Volume	39
Issue number	10
DOIs	https://doi.org/10.1246/cl.2010.1066
Publication status	Published - 2010

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2010.1066

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abstract = "Di(ketoiminato)cobalt complexes have been employed for the alternating copolymerization of alkylene oxide and carbon dioxide. These complexes exhibited not only good catalytic activity for polycarbonate synthesis, but also an excellent selectivity for the formation of carbonate linkages without any ether linkage in the reaction of several alkylene oxides, especially for ethylene oxide.",

author = "Atsushi Okada and Satoshi Kikuchi and Koji Nakano and Kiyoshi Nishioka and Kyoko Nozaki and Tohru Yamada",

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AU - Okada, Atsushi

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AU - Nakano, Koji

AU - Nishioka, Kiyoshi

AU - Nozaki, Kyoko

AU - Yamada, Tohru

PY - 2010

Y1 - 2010

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AB - Di(ketoiminato)cobalt complexes have been employed for the alternating copolymerization of alkylene oxide and carbon dioxide. These complexes exhibited not only good catalytic activity for polycarbonate synthesis, but also an excellent selectivity for the formation of carbonate linkages without any ether linkage in the reaction of several alkylene oxides, especially for ethylene oxide.

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New class of catalysts for alternating copolymerization of alkylene oxide and carbon dioxide

Abstract

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