Abstract
A new mechanism for alkane functionalization by iron(III)-peroxide adducts was proposed, and the importance of electrophilic nature of the metal-peroxide adduct with η1-coordination mode was emphasized. This idea suggests that formation of high-valent iron-oxo species occurs most likely when the metal-peroxide intermediate is activated through electronic interaction with both the peripheral organic group and substrate; the latter two act as an electron donor to the peroxide adduct.
| Original language | English |
|---|---|
| Pages (from-to) | 615-622 |
| Number of pages | 8 |
| Journal | Zeitschrift fur Naturforschung Section C - Journal of Biosciences |
| Volume | 52 |
| Issue number | 9-10 |
| Publication status | Published - 1997 Sep |
| Externally published | Yes |
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Keywords
- Activation of Peroxide Adduct
- Alkane Functionalization
- Electrophilicity of Metal-peroxide
- Iron(III)-peroxide Adduct
ASJC Scopus subject areas
- Agricultural and Biological Sciences(all)
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
Cite this
New insight into reaction of iron(III)-peroxide adduct with alkanes : An alternative model for cytochrome P-450 and methane monooxygenase. / Nishida, Yuzo; Ito, Sayo; Okuno, Takashi; Ohba, Shigeru.
In: Zeitschrift fur Naturforschung Section C - Journal of Biosciences, Vol. 52, No. 9-10, 09.1997, p. 615-622.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - New insight into reaction of iron(III)-peroxide adduct with alkanes
T2 - An alternative model for cytochrome P-450 and methane monooxygenase
AU - Nishida, Yuzo
AU - Ito, Sayo
AU - Okuno, Takashi
AU - Ohba, Shigeru
PY - 1997/9
Y1 - 1997/9
N2 - A new mechanism for alkane functionalization by iron(III)-peroxide adducts was proposed, and the importance of electrophilic nature of the metal-peroxide adduct with η1-coordination mode was emphasized. This idea suggests that formation of high-valent iron-oxo species occurs most likely when the metal-peroxide intermediate is activated through electronic interaction with both the peripheral organic group and substrate; the latter two act as an electron donor to the peroxide adduct.
AB - A new mechanism for alkane functionalization by iron(III)-peroxide adducts was proposed, and the importance of electrophilic nature of the metal-peroxide adduct with η1-coordination mode was emphasized. This idea suggests that formation of high-valent iron-oxo species occurs most likely when the metal-peroxide intermediate is activated through electronic interaction with both the peripheral organic group and substrate; the latter two act as an electron donor to the peroxide adduct.
KW - Activation of Peroxide Adduct
KW - Alkane Functionalization
KW - Electrophilicity of Metal-peroxide
KW - Iron(III)-peroxide Adduct
UR - http://www.scopus.com/inward/record.url?scp=0030779583&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030779583&partnerID=8YFLogxK
M3 - Article
VL - 52
SP - 615
EP - 622
JO - Zeitschrift fur Naturforschung - Section C Journal of Biosciences
JF - Zeitschrift fur Naturforschung - Section C Journal of Biosciences
SN - 0939-5075
IS - 9-10
ER -