New protocol for the siteselective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions

Fumitoshi Kakiuchi, Taisuke Sato, Takuya Tsujimoto, Masakazu Yamauchi, Naoto Chatani, Shinji Murai

Research output: Contribution to journalArticle

75 Citations (Scopus)

Abstract

Catalyst-specific C-H/olefin as well as C-H/acetylene coupling has been accomplished for aromatics which contain both keto and imino substituents by simply changing the catalyst. By using Ru(H)2(CO)(PPh3)3 as the catalyst, the C-H bond at the position ortho to the carbonyl group reacted to add across an olefin. When Ru3(CO)12 is used as the catalyst, the C-H bond at the position ortho to the imino group reacted with the olefin.

Original languageEnglish
Pages (from-to)1053-1054
Number of pages2
JournalChemistry Letters
Issue number10
Publication statusPublished - 1998
Externally publishedYes

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Aromatic compounds
Alkylation
Alkenes
Catalysts
Carbon Monoxide
Acetylene

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Kakiuchi, F., Sato, T., Tsujimoto, T., Yamauchi, M., Chatani, N., & Murai, S. (1998). New protocol for the siteselective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions. Chemistry Letters, (10), 1053-1054.

New protocol for the siteselective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions. / Kakiuchi, Fumitoshi; Sato, Taisuke; Tsujimoto, Takuya; Yamauchi, Masakazu; Chatani, Naoto; Murai, Shinji.

In: Chemistry Letters, No. 10, 1998, p. 1053-1054.

Research output: Contribution to journalArticle

Kakiuchi, F, Sato, T, Tsujimoto, T, Yamauchi, M, Chatani, N & Murai, S 1998, 'New protocol for the siteselective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions', Chemistry Letters, no. 10, pp. 1053-1054.
Kakiuchi, Fumitoshi ; Sato, Taisuke ; Tsujimoto, Takuya ; Yamauchi, Masakazu ; Chatani, Naoto ; Murai, Shinji. / New protocol for the siteselective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions. In: Chemistry Letters. 1998 ; No. 10. pp. 1053-1054.
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