Newly designed catalysts for the enantioselective borohydride reduction: Prediction from the theoretical analysis

Taketo Ikeno; Izumi Iwakura; Atsushi Shibahara; Miho Hatanaka; Ai Kokura; Saiko Tanaka; Takushi Nagata; Tohru Yamada

doi:10.1246/cl.2007.738

Newly designed catalysts for the enantioselective borohydride reduction: Prediction from the theoretical analysis

Taketo Ikeno, Izumi Iwakura, Atsushi Shibahara, Miho Hatanaka, Ai Kokura, Saiko Tanaka, Takushi Nagata, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

For the catalytic enantioselective borohydride reduction, the theoretical simulation of various axial groups in Co complex catalysts predicted that the Co-carbene complexes could be employed as efficient catalysts. The newly designed complexes generated from the Co complex and methyl diazoacetate made it possible to catalyze the enantioselective borohydride reduction in a halogen-free solvent.

Original language	English
Pages (from-to)	738-739
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	6
DOIs	https://doi.org/10.1246/cl.2007.738
Publication status	Published - 2007 Jun 5

ASJC Scopus subject areas

Chemistry(all)

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abstract = "For the catalytic enantioselective borohydride reduction, the theoretical simulation of various axial groups in Co complex catalysts predicted that the Co-carbene complexes could be employed as efficient catalysts. The newly designed complexes generated from the Co complex and methyl diazoacetate made it possible to catalyze the enantioselective borohydride reduction in a halogen-free solvent.",

author = "Taketo Ikeno and Izumi Iwakura and Atsushi Shibahara and Miho Hatanaka and Ai Kokura and Saiko Tanaka and Takushi Nagata and Tohru Yamada",

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AU - Ikeno, Taketo

AU - Iwakura, Izumi

AU - Shibahara, Atsushi

AU - Hatanaka, Miho

AU - Kokura, Ai

AU - Tanaka, Saiko

AU - Nagata, Takushi

AU - Yamada, Tohru

PY - 2007/6/5

Y1 - 2007/6/5

N2 - For the catalytic enantioselective borohydride reduction, the theoretical simulation of various axial groups in Co complex catalysts predicted that the Co-carbene complexes could be employed as efficient catalysts. The newly designed complexes generated from the Co complex and methyl diazoacetate made it possible to catalyze the enantioselective borohydride reduction in a halogen-free solvent.

AB - For the catalytic enantioselective borohydride reduction, the theoretical simulation of various axial groups in Co complex catalysts predicted that the Co-carbene complexes could be employed as efficient catalysts. The newly designed complexes generated from the Co complex and methyl diazoacetate made it possible to catalyze the enantioselective borohydride reduction in a halogen-free solvent.

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Newly designed catalysts for the enantioselective borohydride reduction: Prediction from the theoretical analysis

Abstract

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