Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex

Hirotaka Tanaka, Kentaro Hashimoto, Kyosuke Suzuki, Yasunori Kitaichi, Mitsuo Sato, Taketo Ikeno, Tohru Yamada

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Dinitrogen oxide was employed as a clean oxidant for various oxidations in the presence of a catalytic amount of dioxoruthenium tetramesitylporphyrin complex (Ru(tmp)(O)2). A variety of olefins, secondary alcohols, and benzyl alcohols were smoothly oxidized to the corresponding epoxides, ketones, and aldehydes in high yields. In the oxidation of 9,10-dihydroanthracene derivatives, the competitive reactions affording anthraquinones and anthracenes could be regulated by the reaction conditions. At a high temperature (200°C), anthraquinones were selectively produced, while the anthracenes were selectively produced by the addition of sulfuric acid.

Original languageEnglish
Pages (from-to)1905-1914
Number of pages10
JournalBulletin of the Chemical Society of Japan
Volume77
Issue number10
DOIs
Publication statusPublished - 2004 Oct

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Anthracenes
Anthraquinones
Ruthenium
Porphyrins
Nitrous Oxide
Benzyl Alcohols
Oxidation
Epoxy Compounds
Alkenes
Ketones
Oxidants
Aldehydes
Oxides
Alcohols
Derivatives
Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Tanaka, H., Hashimoto, K., Suzuki, K., Kitaichi, Y., Sato, M., Ikeno, T., & Yamada, T. (2004). Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex. Bulletin of the Chemical Society of Japan, 77(10), 1905-1914. https://doi.org/10.1246/bcsj.77.1905

Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex. / Tanaka, Hirotaka; Hashimoto, Kentaro; Suzuki, Kyosuke; Kitaichi, Yasunori; Sato, Mitsuo; Ikeno, Taketo; Yamada, Tohru.

In: Bulletin of the Chemical Society of Japan, Vol. 77, No. 10, 10.2004, p. 1905-1914.

Research output: Contribution to journalArticle

Tanaka, H, Hashimoto, K, Suzuki, K, Kitaichi, Y, Sato, M, Ikeno, T & Yamada, T 2004, 'Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex', Bulletin of the Chemical Society of Japan, vol. 77, no. 10, pp. 1905-1914. https://doi.org/10.1246/bcsj.77.1905
Tanaka H, Hashimoto K, Suzuki K, Kitaichi Y, Sato M, Ikeno T et al. Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex. Bulletin of the Chemical Society of Japan. 2004 Oct;77(10):1905-1914. https://doi.org/10.1246/bcsj.77.1905
Tanaka, Hirotaka ; Hashimoto, Kentaro ; Suzuki, Kyosuke ; Kitaichi, Yasunori ; Sato, Mitsuo ; Ikeno, Taketo ; Yamada, Tohru. / Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex. In: Bulletin of the Chemical Society of Japan. 2004 ; Vol. 77, No. 10. pp. 1905-1914.
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