Nitrous oxide oxidation of secondary and benzylic alcohols using ruthenium complex catalyst

Kentaro Hashimoto; Yasunori Kitaichi; Hirotaka Tanaka; Taketo Ikeno; Tohru Yamada

doi:10.1246/cl.2001.922

Nitrous oxide oxidation of secondary and benzylic alcohols using ruthenium complex catalyst

Kentaro Hashimoto, Yasunori Kitaichi, Hirotaka Tanaka, Taketo Ikeno, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Catalytic N₂O oxidation of various secondary and benzylic alcohols using a ruthenium porphyrin complex is presented. Both secondary and benzylic alcohols were smoothly consumed to give the corresponding ketones and aldehydes in high yields. Nitrous oxide (N₂O) is expected to be a new terminal oxidant producing only dinitrogen gas as the only by-product to provide a less wasteful process.

Original language	English
Pages (from-to)	922-923
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.2001.922
Publication status	Published - 2001 Jan 1

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Catalytic N2O oxidation of various secondary and benzylic alcohols using a ruthenium porphyrin complex is presented. Both secondary and benzylic alcohols were smoothly consumed to give the corresponding ketones and aldehydes in high yields. Nitrous oxide (N2O) is expected to be a new terminal oxidant producing only dinitrogen gas as the only by-product to provide a less wasteful process.",

author = "Kentaro Hashimoto and Yasunori Kitaichi and Hirotaka Tanaka and Taketo Ikeno and Tohru Yamada",

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T1 - Nitrous oxide oxidation of secondary and benzylic alcohols using ruthenium complex catalyst

AU - Hashimoto, Kentaro

AU - Kitaichi, Yasunori

AU - Tanaka, Hirotaka

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2001/1/1

Y1 - 2001/1/1

N2 - Catalytic N2O oxidation of various secondary and benzylic alcohols using a ruthenium porphyrin complex is presented. Both secondary and benzylic alcohols were smoothly consumed to give the corresponding ketones and aldehydes in high yields. Nitrous oxide (N2O) is expected to be a new terminal oxidant producing only dinitrogen gas as the only by-product to provide a less wasteful process.

AB - Catalytic N2O oxidation of various secondary and benzylic alcohols using a ruthenium porphyrin complex is presented. Both secondary and benzylic alcohols were smoothly consumed to give the corresponding ketones and aldehydes in high yields. Nitrous oxide (N2O) is expected to be a new terminal oxidant producing only dinitrogen gas as the only by-product to provide a less wasteful process.

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DO - 10.1246/cl.2001.922

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JF - Chemistry Letters

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