Nitrous oxide oxidation of secondary and benzylic alcohols using ruthenium complex catalyst

Kentaro Hashimoto, Yasunori Kitaichi, Hirotaka Tanaka, Taketo Ikeno, Tohru Yamada

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Catalytic N2O oxidation of various secondary and benzylic alcohols using a ruthenium porphyrin complex is presented. Both secondary and benzylic alcohols were smoothly consumed to give the corresponding ketones and aldehydes in high yields. Nitrous oxide (N2O) is expected to be a new terminal oxidant producing only dinitrogen gas as the only by-product to provide a less wasteful process.

Original languageEnglish
Pages (from-to)922-923
Number of pages2
JournalChemistry Letters
Issue number9
Publication statusPublished - 2001

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Ruthenium
Nitrous Oxide
Alcohols
Oxidation
Catalysts
Catalytic oxidation
Porphyrins
Ketones
Oxidants
Aldehydes
Byproducts
Gases

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Nitrous oxide oxidation of secondary and benzylic alcohols using ruthenium complex catalyst. / Hashimoto, Kentaro; Kitaichi, Yasunori; Tanaka, Hirotaka; Ikeno, Taketo; Yamada, Tohru.

In: Chemistry Letters, No. 9, 2001, p. 922-923.

Research output: Contribution to journalArticle

Hashimoto, Kentaro ; Kitaichi, Yasunori ; Tanaka, Hirotaka ; Ikeno, Taketo ; Yamada, Tohru. / Nitrous oxide oxidation of secondary and benzylic alcohols using ruthenium complex catalyst. In: Chemistry Letters. 2001 ; No. 9. pp. 922-923.
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AU - Yamada, Tohru

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