N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes: Syntheses, crystal structures and magnetic properties

Jing Hua Wang; Peng Fei Yan; Guang Ming Li; Ju Wen Zhang; Peng Chen; Masayuki Suda; Yasuaki Einaga

doi:10.1016/j.ica.2010.05.030

N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes: Syntheses, crystal structures and magnetic properties

Jing Hua Wang, Peng Fei Yan, Guang Ming Li, Ju Wen Zhang, Peng Chen, Masayuki Suda, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H₂L}Sm(NO ₃)₃]₂·H₂O (1), [{H ₂L}Gd(NO₃)₃]₄·CH ₃OH (2), [{H₂L}Lu(NO₃)₃] ₄·H₂O (3) (H₂L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH₃COO)(CH ₃COOH)Gd(NO₃)₂] (4), [{LNi(MeOH) ₂}Gd(NO₃)₃]·2MeOH (5) and [{(L)Zn(HNO₃)}Gd(NO₃)₃]·NO ₃·H₃O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.

Original language	English
Pages (from-to)	3706-3713
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	363
Issue number	14
DOIs	https://doi.org/10.1016/j.ica.2010.05.030
Publication status	Published - 2010 Nov 25

Keywords

Heterodinuclear 3d-4f
Lanthanide
Magnetism
Salen like
Structure
Synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{3c75adb97a9343279eab0604b699af47,

title = "N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes: Syntheses, crystal structures and magnetic properties",

abstract = "Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO 3)3]2·H2O (1), [{H 2L}Gd(NO3)3]4·CH 3OH (2), [{H2L}Lu(NO3)3] 4·H2O (3) (H2L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH 3COOH)Gd(NO3)2] (4), [{LNi(MeOH) 2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO 3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.",

keywords = "Heterodinuclear 3d-4f, Lanthanide, Magnetism, Salen like, Structure, Synthesis",

author = "Wang, {Jing Hua} and Yan, {Peng Fei} and Li, {Guang Ming} and Zhang, {Ju Wen} and Peng Chen and Masayuki Suda and Yasuaki Einaga",

note = "Funding Information: This work is financially supported by the National Natural Science Foundation of China (Nos. 20872030 and 20972043 ), Heilongjiang Province (Nos. GC09A402 , 2009RFXXG201 and 2010td03) and Heilongjiang University . ",

year = "2010",

month = nov,

day = "25",

doi = "10.1016/j.ica.2010.05.030",

language = "English",

volume = "363",

pages = "3706--3713",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "14",

}

TY - JOUR

T1 - N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes

T2 - Syntheses, crystal structures and magnetic properties

AU - Wang, Jing Hua

AU - Yan, Peng Fei

AU - Li, Guang Ming

AU - Zhang, Ju Wen

AU - Chen, Peng

AU - Suda, Masayuki

AU - Einaga, Yasuaki

N1 - Funding Information: This work is financially supported by the National Natural Science Foundation of China (Nos. 20872030 and 20972043 ), Heilongjiang Province (Nos. GC09A402 , 2009RFXXG201 and 2010td03) and Heilongjiang University .

PY - 2010/11/25

Y1 - 2010/11/25

N2 - Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO 3)3]2·H2O (1), [{H 2L}Gd(NO3)3]4·CH 3OH (2), [{H2L}Lu(NO3)3] 4·H2O (3) (H2L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH 3COOH)Gd(NO3)2] (4), [{LNi(MeOH) 2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO 3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.

AB - Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO 3)3]2·H2O (1), [{H 2L}Gd(NO3)3]4·CH 3OH (2), [{H2L}Lu(NO3)3] 4·H2O (3) (H2L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH 3COOH)Gd(NO3)2] (4), [{LNi(MeOH) 2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO 3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.

KW - Heterodinuclear 3d-4f

KW - Lanthanide

KW - Magnetism

KW - Salen like

KW - Structure

KW - Synthesis

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U2 - 10.1016/j.ica.2010.05.030

DO - 10.1016/j.ica.2010.05.030

M3 - Article

AN - SCOPUS:77957974122

SN - 0020-1693

VL - 363

SP - 3706

EP - 3713

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 14

ER -

N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes: Syntheses, crystal structures and magnetic properties

Abstract

Keywords

ASJC Scopus subject areas

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