N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes

Syntheses, crystal structures and magnetic properties

Jing Hua Wang, Peng Fei Yan, Guang Ming Li, Ju Wen Zhang, Peng Chen, Masayuki Suda, Yasuaki Einaga

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO 3)3]2·H2O (1), [{H 2L}Gd(NO3)3]4·CH 3OH (2), [{H2L}Lu(NO3)3] 4·H2O (3) (H2L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH 3COOH)Gd(NO3)2] (4), [{LNi(MeOH) 2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO 3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.

Original languageEnglish
Pages (from-to)3706-3713
Number of pages8
JournalInorganica Chimica Acta
Volume363
Issue number14
DOIs
Publication statusPublished - 2010 Nov 25

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Keywords

  • Heterodinuclear 3d-4f
  • Lanthanide
  • Magnetism
  • Salen like
  • Structure
  • Synthesis

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes : Syntheses, crystal structures and magnetic properties. / Wang, Jing Hua; Yan, Peng Fei; Li, Guang Ming; Zhang, Ju Wen; Chen, Peng; Suda, Masayuki; Einaga, Yasuaki.

In: Inorganica Chimica Acta, Vol. 363, No. 14, 25.11.2010, p. 3706-3713.

Research output: Contribution to journalArticle

Wang, Jing Hua ; Yan, Peng Fei ; Li, Guang Ming ; Zhang, Ju Wen ; Chen, Peng ; Suda, Masayuki ; Einaga, Yasuaki. / N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d-4f heterodinuclear complexes : Syntheses, crystal structures and magnetic properties. In: Inorganica Chimica Acta. 2010 ; Vol. 363, No. 14. pp. 3706-3713.
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abstract = "Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO 3)3]2·H2O (1), [{H 2L}Gd(NO3)3]4·CH 3OH (2), [{H2L}Lu(NO3)3] 4·H2O (3) (H2L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH 3COOH)Gd(NO3)2] (4), [{LNi(MeOH) 2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO 3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.",
keywords = "Heterodinuclear 3d-4f, Lanthanide, Magnetism, Salen like, Structure, Synthesis",
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T2 - Syntheses, crystal structures and magnetic properties

AU - Wang, Jing Hua

AU - Yan, Peng Fei

AU - Li, Guang Ming

AU - Zhang, Ju Wen

AU - Chen, Peng

AU - Suda, Masayuki

AU - Einaga, Yasuaki

PY - 2010/11/25

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N2 - Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO 3)3]2·H2O (1), [{H 2L}Gd(NO3)3]4·CH 3OH (2), [{H2L}Lu(NO3)3] 4·H2O (3) (H2L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH 3COOH)Gd(NO3)2] (4), [{LNi(MeOH) 2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO 3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.

AB - Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3- diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO 3)3]2·H2O (1), [{H 2L}Gd(NO3)3]4·CH 3OH (2), [{H2L}Lu(NO3)3] 4·H2O (3) (H2L = N,N′-bis(2- hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH 3COOH)Gd(NO3)2] (4), [{LNi(MeOH) 2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO 3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1-3 are isomorphic with unique dimeric topology. Complexes 4-6 are of discrete 3d-4f dinuclear cores. Magnetic properties of complexes 2 and 4-6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.

KW - Heterodinuclear 3d-4f

KW - Lanthanide

KW - Magnetism

KW - Salen like

KW - Structure

KW - Synthesis

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