[N,N′-Bis(2-methoxycarbonyl-3-oxobutylidene)-ethylenediaminato- κ4O,N,N′O′]cobalt(II)

Takashiro Akitsu, Izumi Iwakura, Hirotaka Tanaka, Taketo Ikeno, Yasuaki Einaga, Tohru Yamada

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The title compound, [Co(C14H18N2O 6)], is the first structurally characterized example of a β-ketoiminato CoII complex without axial ligands. It adopts a square-planar cis-[CoN2O2] coordination geometry, and lies on a mirror plane. The planar complexes are stacked along 21 screw axes parallel to b to form columns, the Co⋯Co distance in the column being 3.5213 (2) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number2
DOIs
Publication statusPublished - 2004 Feb

Fingerprint

Cocos
Cobalt
Mirrors
cobalt
Ligands
Geometry
screws
mirrors
ligands
geometry

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

[N,N′-Bis(2-methoxycarbonyl-3-oxobutylidene)-ethylenediaminato- κ4O,N,N′O′]cobalt(II). / Akitsu, Takashiro; Iwakura, Izumi; Tanaka, Hirotaka; Ikeno, Taketo; Einaga, Yasuaki; Yamada, Tohru.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 2, 02.2004.

Research output: Contribution to journalArticle

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AU - Iwakura, Izumi

AU - Tanaka, Hirotaka

AU - Ikeno, Taketo

AU - Einaga, Yasuaki

AU - Yamada, Tohru

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