[N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)

Gakuse Hoshina, Shigeru Ohba, Masanobu Tsuchimoto

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title complex, [VO(C30H24N2O4)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the VIV atom is distorted square pyramidal. The V=O distance is 1.588 (3) Å, and the V atom is displaced by 0.57 (1) Å from the N2O2 coordination plane towards the apical oxo ligand. † Alternative name: {4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′}oxovanadium(IV).

Original languageEnglish
Pages (from-to)1451-1453
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number9
Publication statusPublished - 1999 Sep 15

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Ligands
Atoms
ligands
Schiff Bases
imines
Names
atoms
Charge transfer
charge transfer
Crystals
Geometry
geometry
crystals
diphenyl
oxovanadium IV

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

[N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV). / Hoshina, Gakuse; Ohba, Shigeru; Tsuchimoto, Masanobu.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 55, No. 9, 15.09.1999, p. 1451-1453.

Research output: Contribution to journalArticle

Hoshina, Gakuse ; Ohba, Shigeru ; Tsuchimoto, Masanobu. / [N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV). In: Acta Crystallographica Section C: Crystal Structure Communications. 1999 ; Vol. 55, No. 9. pp. 1451-1453.
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