[N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)

Gakuse Hoshina, Shigeru Ohba, Masanobu Tsuchimoto

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title complex, [VO(C30H24N2O4)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the VIV atom is distorted square pyramidal. The V=O distance is 1.588 (3) Å, and the V atom is displaced by 0.57 (1) Å from the N2O2 coordination plane towards the apical oxo ligand. † Alternative name: {4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′}oxovanadium(IV).

Original languageEnglish
Pages (from-to)1451-1453
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number9
DOIs
Publication statusPublished - 1999 Sep 15

    Fingerprint

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this