[N,N′-Bis(salicylidene)-1,2-diphenyl-(RS, SR)-1,2-ethanediaminato]-nickel(II)

Gakuse Hoshina, Masanobu Tsuchimoto, Shigeru Ohba

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Investigations reveal that in the crystals of [N,N'-Bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]-nickel(Ni)(II) the coordination geometry around the Ni atom is square planar with a slight tetrahedral distortion. The five-membered N,N'-chelate ring adopts a distorted gauche conformation with the two phenyl groups in axial and equatorial orientations. [N,N'-Bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]-nickel(Ni)(II) compound has been prepared by the reaction of a hot methanol solution (30 ml) of nickel(II) acetate tetrahydrate with the Schiff base ligand H(sal-meso-stien).

Original languageEnglish
Pages (from-to)e122
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number4
Publication statusPublished - 2000

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Nickel
Nickel compounds
Schiff Bases
Methanol
Conformations
Ligands
Atoms
Crystals
Geometry
diphenyl

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

[N,N′-Bis(salicylidene)-1,2-diphenyl-(RS, SR)-1,2-ethanediaminato]-nickel(II). / Hoshina, Gakuse; Tsuchimoto, Masanobu; Ohba, Shigeru.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 4, 2000, p. e122.

Research output: Contribution to journalArticle

Hoshina, Gakuse ; Tsuchimoto, Masanobu ; Ohba, Shigeru. / [N,N′-Bis(salicylidene)-1,2-diphenyl-(RS, SR)-1,2-ethanediaminato]-nickel(II). In: Acta Crystallographica Section C: Crystal Structure Communications. 2000 ; Vol. 56, No. 4. pp. e122.
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