[N,N′-Bis(salicylidene)-1,2-diphenyl-(RS, SR)-1,2-ethanediaminato]-nickel(II)

Gakuse Hoshina, Masanobu Tsuchimoto, Shigeru Ohba

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Investigations reveal that in the crystals of [N,N'-Bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]-nickel(Ni)(II) the coordination geometry around the Ni atom is square planar with a slight tetrahedral distortion. The five-membered N,N'-chelate ring adopts a distorted gauche conformation with the two phenyl groups in axial and equatorial orientations. [N,N'-Bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]-nickel(Ni)(II) compound has been prepared by the reaction of a hot methanol solution (30 ml) of nickel(II) acetate tetrahydrate with the Schiff base ligand H(sal-meso-stien).

Original languageEnglish
Pages (from-to)e122
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number4
DOIs
Publication statusPublished - 2000 Jan 1

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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